Solid State Ionics for BatteriesM. Tatsumisago, M. Wakihara, C. Iwakura, S. Kohjiya, I. Tanaka Springer Science & Business Media, 24 mag 2005 - 276 pagine In this book, recent progress in batteries is firstly reviewed by researchers in three leading Japanese battery companies, SONY, Matsushita and Sanyo, and then the future problems in battery development are stated. Then, recent development of solid state ionics for batteries, including lithium ion battery, metal-hydride battery, and fuel cells, are reviewed. A battery comprises essentially three components: positive electrode, negative electrode, and electrolyte. Each component is discussed for the construction of all-solid-state Batteries. Theoretical understanding of properties of battery materials by using molecular orbital calculations is also introduced. |
Sommario
Introduction | 1 |
Recent progress in batteries and future problems | 5 |
213 Lithium polymer battery | 7 |
214 Future of LIB and LPB | 11 |
22 Recent technologies on materials for advanced lithium rechargeable batteries Panasonic | 12 |
223 Active materials for negative electrodes | 13 |
224 Electrolytes | 14 |
225 Concluding remarks | 17 |
622 High molar mass polyoxyethylenes | 192 |
623 Polyoxyethylene networks | 196 |
63 Viscosity behaviors of branched polyoxyethylenes | 199 |
64 Composite electrolytes based on branched polyoxyethylene | 200 |
642 Hybrid solid electrolytes from oxysulfide glass and branched polyoxyethylene | 201 |
65 Effect of elongation of elastomer electrolytes on conductivity | 206 |
66 lonene elastomers for polymer solid electrolytes | 209 |
662 Polymer solid electrolytes prepared from polyoxytetramethylenes | 211 |
23 Development of secondary battery electrode materials toward high energy and power density Sanyo | 19 |
232 Approach to high power density of nickelmetal hydride batteries 7 | 20 |
233 Approach to high energy density of lithium secondary batteries 28 | 24 |
234 Conclusions | 28 |
Recent development of amorphous solid electrolytes and their application to solidstate batteries | 31 |
32 Lithium ion conductors 321 Solid electrolytes | 32 |
322 Electrode materials | 42 |
323 Allsolidstate lithium secondary batteries | 53 |
324 Thin film batteries | 64 |
33 Proton conductors | 73 |
332 Protonconducting composite materials 3321 Background | 80 |
333 Protonconducting hybrid materials | 87 |
34 Conclusions | 93 |
Recent development of electrode materials in lithium ion batteries | 95 |
412 Crystal structure of spinel type phase | 97 |
413 Electrochemical properties of LiNi05Mni5O4 and | 99 |
414 Coulombic potential calculation of diffusion path for ordered and disordered Fd3m spinels | 100 |
415 Conclusions | 102 |
423 Characterization of electrodesolid electrolyte interface in solidstate batteries | 126 |
Construction of solidsolid interface between hydrogen storage alloy electrode and solid electrolyte for battery application | 133 |
52 Hydrogen storage alloy electrodepolymer hydrogel electrolyte interface | 136 |
522 Application of polymer hydrogel electrolyte to nickelmetal hydride batteries | 146 |
523 Application of polymer hydrogel electrolyte to electric doublelayer capacitors | 159 |
524 Preparation and characterization of protonconducting polymeric gel electrolytes | 162 |
532 Preparation characterization and application of inorganic oxide solid electrolytes | 177 |
54 Conclusions | 185 |
61 Introduction Role of rubbery state for ionic conduction | 187 |
62 Branched polyoxyethylenes as polymer solid electrolytes | 191 |
663 Viologentype polyoxytetramethylene ionene elastomers | 212 |
664 Aliphatic polyoxytetramethylene ionene elastomer | 216 |
67 Further usefulness of rubbery matrix | 221 |
68 Concluding remarks | 223 |
722 Computational procedure | 232 |
723 Electronic and bonding states of LiCoOi and CoC2 | 233 |
724 Differences in bonding states among Li | 237 |
725 Conclusion | 238 |
73 First principles study on factors determining voltages of layered LiMO2 M Ti Ni | 240 |
732 Computational procedure | 241 |
733 Molecular orbital calculations using model clusters | 242 |
734 FLAPW bandstructure calculations for LiMO2 and MO2 | 245 |
735 Conclusion | 248 |
| 250 | |
742 PWPP calculation for structural optimization | 252 |
744 Lattice parameters and relaxation by delithiation | 254 |
746 Average voltage | 256 |
| 258 | |
752 Computational procedure | 259 |
753 Defects of oxygen vacancy type | 260 |
simple interstitial atoms | 262 |
with occupation of Mn at the 8a position | 264 |
756 Local electronic structures around defects | 265 |
757 Discussion | 267 |
| 268 | |
76 Summary and conclusions | 269 |
| 273 | |
Altre edizioni - Visualizza tutto
Solid State Ionics for Batteries M. Tatsumisago,M. Wakihara,C. Iwakura,S. Kohjiya,I. Tanaka Anteprima limitata - 2006 |
Solid State Ionics for Batteries M. Tatsumisago,M. Wakihara,C. Iwakura,S. Kohjiya,I. Tanaka Anteprima non disponibile - 2014 |
Solid State Ionics for Batteries M. Tatsumisago,M. Wakihara,C. Iwakura,S. Kohjiya,I. Tanaka Anteprima non disponibile - 2009 |
Parole e frasi comuni
acid all-solid-state batteries alloy amorphous anions anode atoms calculations capacity retention cathode Cell voltage charge and discharge charge-discharge curves charge-discharge cycle Chem clusters cm-¹ composite sheet crystalline current density defects discharge capacity doped elastomers Electrochem electrolyte solutions energy density exchange current density FLAPW formation energy fuel cells glass-ceramics Hayashi hybrid films hydroxide Ikeda increase inorganic interface interstitial ionic conductivity KOH aqueous solution Kohjiya Lewis acid LiClO4 LiCoO2 LiMn2O4 LiMO2 lithium batteries lithium ion batteries lithium salt matrix Matsuda Minami molar mass molecular negative electrode Ni/MH cells Osaka Prefecture University oxide oxygen oxysulfide glass P/Si PEG-borate ester PEGDME polymer electrolytes polymer hydrogel electrolyte polymeric positive electrode materials potential POTM Power Sources prepared proton conductivity reaction redox room temperature secondary batteries shown in Fig shows silica gels solid electrolytes Solid State Ionics solid-state spinel structure Tadanaga Tatsumisago thin film batteries transition-metal transport number voltage
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