Molecular Optical Activity and the Chiral Discriminations
Cambridge University Press, 14 ott 1982 - 273 pagine
This book, first published in 1982, presents a comprehensive introduction to studies of the singular chemical and physical properties of chiral molecules, both organic and inorganic. The topics discussed include the physical basis of the optical activity and the selective interactions of chiral molecules, and the general principles underlying enantiomer separation and asymmetric synthesis. In addition, the successive stages in the development of structural theory that were dependent upon the study of optically active materials are briefly surveyed.
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OPTICAL ROTATORY DISPERSION AND CIRCULAR DICHROISM
GENERAL MECHANISMS FOR OPTICAL ACTIVITY
CHIRAL TRANSITIONMETAL COMPLEXES
CHIRAL ENERGY DISCRIMINATION
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achiral acid addition allowed analogues angle asymmetric atom axis band bond carbonyl CD absorption centre charge chelate rings chemical chiral chromophore circular dichroism complex component compounds configuration conformation containing contribution coordination corresponding coupling crystal crystallisation curves derivatives determination diastereomeric differential dimer dipole direction discrimination dissymmetry electric electric-dipole electronic employed enantiomer enantiomeric energy excess excitation field fraction frequency function given gives helical induced interaction isomer ligand lower magnetic-dipole magnitude Mason measured mechanism metal method mixture mode molecular molecules monomer negative observed octahedral optical activity orbital orientation origin parallel particular phase plane polarizability polarized positive potential provides racemic radiation range ratio refer region relative resolution respectively resultant rotational strength rule salt scattering separation solution space groups spectrum structure substituent group symmetry temperature tetrahedral theory transition vibrational wavelength X-ray
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Advances in Complex Electromagnetic Materials
North Atlantic Treaty Organization. Scientific Affairs Division
Visualizzazione frammento - 1997