Mechanism and Synthesis

Copertina anteriore
Peter Taylor, Lesley E. Smart, Giles Clark
Royal Society of Chemistry, 2002 - 368 pagine
This book pursues possible strategies for synthesising mainly organic compounds, particularly those of interest to the health sector and related industries. Topics covered include addition reactions of aldehydes and ketones; the use of organometallic reagents to form carbon-carbon bonds (eg Grignard reagents); and radical reactions, including selectivity and chain reactions. Retrosynthetic analysis is introduced as a strategy for developing syntheses, along with biochemical pathways. Mechanism and Synthesis concludes with a Case Study on polymers, which demonstrates how chain reactions can be used to build up useful materials with specific properties, such as contact lenses. The Molecular World series provides an integrated introduction to all branches of chemistry for both students wishing to specialise and those wishing to gain a broad understanding of chemistry and its relevance to the everyday world and to other areas of science. The books, with their Case Studies and accompanying multi-media interactive CD-ROMs, will also provide valuable resource material for teachers and lecturers. (The CD-ROMs are designed for use on a PC running Windows 95, 98, ME or 2000.)
 

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Sommario

NUCLEOPHILIC ATTACK AT THE CARBONYL GROUP
21
CONCLUSION
56
ANSWERS AND COMMENTS
63
ACKNOWLEDGEMENTS
74
SYNTHETIC APPLICATIONS
75
ORGANOLITHIUM AND ORGANOSODIUM
93
ORGANOCOPPER COMPOUNDS
101
APPENDIX SUMMARY OF ORGANOMETALLIC
111
CX BONDS
196
CONTROL IN SYNTHESIS
236
FURTHER FACTORS AFFECTING THE CHOICE
248
LEARNING OUTCOMES
260
ANSWERS TO EXERCISES
273
FURTHER READING
279
THE LABORATORY SYNTHESIS
290
A BIOCHEMICAL INTERLUDE
299

RADICAL REACTIONS
121
REACTIONS OF RADICALS
131
RADICAL CHAIN REACTIONS
140
RADICAL FRAGMENTATION REACTIONS
160
STRATEGY AND METHODOLOGY
177
PLANNING A SYNTHESIS
190
THE CHEMISTRY OF TERPENE BIOSYNTHESIS
310
LEARNING OUTCOMES
322
POLYMER CHEMISTRY
327
POLYACRYLAMIDE
345
Copyright

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