Analytical Chemistry |
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Pagina 314
Oxidation - Reduction Titrations agent or to the trivalent state for titration with a
reducing agent . The electrode potential for an auxiliary reagent must be such as
to assure quantitative conversion of the analyte to the desired oxidation state .
Oxidation - Reduction Titrations agent or to the trivalent state for titration with a
reducing agent . The electrode potential for an auxiliary reagent must be such as
to assure quantitative conversion of the analyte to the desired oxidation state .
Pagina 316
Oxidation - Reduction Titrations TABLE 13 - 1 Uses of the Walden Reductor and
the Jones Reductor " WALDEN ... 2e + U022 + + 4H * → U4 + + 2H2O e + Fe3 +
→ Fe2 + Cu2 + reduced to metallic Cu 3e + H2M004 + 6H * → Mo7 + + 4H20 2e
...
Oxidation - Reduction Titrations TABLE 13 - 1 Uses of the Walden Reductor and
the Jones Reductor " WALDEN ... 2e + U022 + + 4H * → U4 + + 2H2O e + Fe3 +
→ Fe2 + Cu2 + reduced to metallic Cu 3e + H2M004 + 6H * → Mo7 + + 4H20 2e
...
Pagina 420
Most metallic cations , for example , are reduced at the dropping electrode to form
a metal amalgam or a lower oxidation state . Even the alkali - and alkaline - earth
metals are reducible , provided the supporting electrolyte used does not ...
Most metallic cations , for example , are reduced at the dropping electrode to form
a metal amalgam or a lower oxidation state . Even the alkali - and alkaline - earth
metals are reducible , provided the supporting electrolyte used does not ...
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Sommario
Preface | 1 |
A Review of Some Elementary Concepts | 8 |
A Review of Simple Equilibrium Constant | 24 |
Copyright | |
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absorbance absorption acid activity added addition amount analysis analyte application approximately balance base becomes Calculate carbonate cause cell Chapter chemical chloride chromatography color column common complex concentration considered constant containing curve described determined deviation difference dilute direct Discussion dissociation dissolved drop effect electrode employed end point Equation equilibrium equivalence point error example excess exist expression Figure filter flask formation give given glass heating hydrogen hydroxide important increase indicator involves iodine less limited liquid liter mean measurements metal method NaOH needed Neutralization Note obtained occurs organic oxidation phase potassium potential precipitate prepared presence problem Procedure quantity radiation reaction reagent reduced region relative sample separation shown silver sodium solid solubility solution species standard substance surface Table temperature titration volume volumetric weight