Metallocene-based polyolefins: preparation, properties, and technology
The manufacture of polyolefins by metallocene catalysts represents a revolution in the polymer industry. The first, patent for a metallocene catalyst was filed in 1980 but it has been the last five years that have seen a dramatic increase in the volume of research into metallocenes and the maturing of metallocene technology. With contributions from leading experts from the US, Canada, Italy, Scandinavia, Germany and Japan, Metallocene-based Polyolefins gives comprehensive coverage of all areas of metallocene technology: catalyst structure, comonomer incorporation, polymerization mechanisms and conditions, reactor configurations, special properties, rheological and processing behaviour, comparison with conventional polyolefins and fields of application. An essential book for plastics engineers, polymer chemists, physicists, materials scientists and all those working in the plastics manufacturing and processing industries.
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Synthesis Structure and Reactivity
MAOfree Metallocene Catalysts for Ethylene CoPolymerization
Influence of Metallocene Structures on Molecular and Supermolecular
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1-butene a-olefin alkyl alkylalumoxanes AlMe3 aluminum alumoxane Angew anion Appl atactic atoms Brintzinger Brookhart Catal catalyst activity catalyst systems cationic Chem chemical Chien co-workers cocatalyst comonomer complexes compounds concentration coordination copolymerization copolymers Cp2ZrCl2 crystal cyclopentadienyl decrease density distribution Engl equation ethene ethylene ethylene polymerization Ewen Figure formation groups heterogeneous high molecular weight high-pressure process higher homogeneous hydrogen increase indenyl insertion isospecific isotactic Kaminsky Lewis acidity ligands LLDPE Macromol Macromolecules metallocene catalysts metallocene-based methyl microstructure molecular weight monomer Mulhaupt obtained olefin polymerization Organomet Organometallics Piemontesi polyethylene polymer polymerization activity Polymerization conditions polymerization temperature polyolefin polypropylene produced propene propylene propylene polymerization Rapid Commun reacted reaction reactivity ratios Resconi silica Sinn Soga solution solvent Spaleck species steric structure styrene substituents supported catalyst supported metallocene syndiotactic synthesis Table TIBAO toluene transition metal yield Zambelli Ziegler-Natta zirconium zirconocene