Fundamentals of Analytical ChemistryHolt, Rinehart and Winston, 1969 - 835 pagine |
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Pagina 159
... oxalate despite the fact that the latter ion also forms an oxalate of comparable solubility . The separation is possible be- cause equilibrium for magnesium oxalate formation is approached at a much slower rate than that for calcium oxalate ...
... oxalate despite the fact that the latter ion also forms an oxalate of comparable solubility . The separation is possible be- cause equilibrium for magnesium oxalate formation is approached at a much slower rate than that for calcium oxalate ...
Pagina 422
Douglas A. Skoog, Donald M. West. Standardization against Sodium Oxalate Sodium oxalate of certified purity may be purchased from the National Bureau of Standards . Commercial reagent grades of the salt commonly assay 99.9 per- cent or ...
Douglas A. Skoog, Donald M. West. Standardization against Sodium Oxalate Sodium oxalate of certified purity may be purchased from the National Bureau of Standards . Commercial reagent grades of the salt commonly assay 99.9 per- cent or ...
Pagina 429
... oxalate must be exactly 1 in the solution at the time of titration ; to assure this condition , several precautions are necessary . For example , calcium oxalate formed in neutral or ammoniacal solutions is likely to be contaminated ...
... oxalate must be exactly 1 in the solution at the time of titration ; to assure this condition , several precautions are necessary . For example , calcium oxalate formed in neutral or ammoniacal solutions is likely to be contaminated ...
Sommario
1 The Scope of Analytical Chemistry | 1 |
2 Review of Elementary Concepts Important to Analytical Chemistry | 7 |
3 The Evaluation of Analytical Data | 25 |
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2H₂O absorbance absorption acetic acetic acid acid solution addition AgNO3 alkaline analysis analytical anode application aqueous base buffer calcium Calculate carbonate cathode cations cell cerium(IV chemical chloride color complex compounds copper(II coulometric crucible determined dilute dissociation dissolved EDTA electrolyte employed end point equation equilibrium constant equivalence point error ethanol example excess F with respect Fe3+ filter flask formal concentration formation glass H₂O H3O+ half-reaction hydrochloric acid hydrogen ion hydronium ion indicator iodide iodine ion concentration iron(III liquid measurement mercury(II metal method mixture mole/liter NaOH obtained oxalate oxidation particles percent perchloric acid permanganate potassium precipitate procedure quantity radiation reaction reagent reduced result salt sample saturated calomel electrode silver ion sodium solid solubility solution containing solvent species standard hydrogen electrode standard solution substance sulfate sulfuric sulfuric acid temperature tion titration titration curve volume volumetric wavelength weak acid