NMR of Paramagnetic Molecules: Applications to Metallobiomolecules and ModelsElsevier, 15 set 2016 - 508 pagine NMR of Paramagnetic Molecules: Applications to Metallobiomolecules and Models, Second Edition is a self-contained, comprehensive reference for chemists, physicists, and life scientists whose research involves analyzing paramagnetic compounds. Since the previous edition of this book was published, there have been many advancements in the field of paramagnetic NMR spectroscopy. This completely updated and expanded edition contains the latest fundamental theory and methods for mastery of this analytical technique. Users will learn how to interpret the NMR spectra of paramagnetic molecules, improve experimental techniques, and strengthen their understanding of the underlying theory and applications.
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Sommario
1 | |
25 | |
residual dipolar couplings | 61 |
Chapter 4 Relaxation | 77 |
Chapter 5 High resolution solidstate NMR in paramagnetic molecules | 127 |
Chapter 6 Chemical exchange chemical equilibria and dynamics | 151 |
shift and relaxation | 175 |
shift and relaxation | 255 |
Appendix I NMR properties of nuclei | 457 |
Appendix II Dipolar coupling between two spins | 461 |
Appendix III Derivation of the equations for contact shift and relaxation in a simple case | 463 |
Appendix IV Derivation of the pseudocontact shift equations in different forms | 467 |
Appendix V Relaxation by dipolar interaction between two spins | 471 |
Curies law | 477 |
Appendix VII Derivation of the equations related to NOE | 479 |
Appendix VIII Magnetically coupled dimers in the hightemperature limit | 483 |
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NMR of Paramagnetic Molecules: Applications to Metallobiomolecules and Models Ivano Bertini,Claudio Luchinat,Giacomo Parigi,Enrico Ravera Anteprima non disponibile - 2016 |
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