Carbon Dioxide as Chemical FeedstockMichele Aresta John Wiley & Sons, 26 gen 2010 - 414 pagine Filling the need for an up-to-date handbook, this ready reference closely investigates the use of CO2 for ureas, enzymes, carbamates, and isocyanates, as well as its use as a solvent, in electrochemistry, biomass utilization and much more. Edited by an internationally renowned and experienced researcher, this is a comprehensive source for every synthetic chemist in academia and industry. |
Sommario
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3 Autotrophic Carbon Fixation in Biology Pathways Rules and Speculations | 33 |
4 Carbon Dioxide Coordination Chemistry and Reactivity of Coordinated CO2 | 55 |
5 Main Group Element and Transition MetalPromoted Carboxylation of Organic Substrates Alkanes Alkenes Alkynes Aromatics and Others | 89 |
6 The Chemistry of NCO2 Bonds Synthesis of Carbamic Acids and Their Derivatives Isocyanates and Ureas | 121 |
7 Synthesis of Linear and Cyclic Carbonates | 169 |
8 Polymers from Carbon Dioxide Polycarbonates Polythiocarbonates and Polyurethanes | 213 |
9 InSitu Study of Carbon Deposition during CO2 Reforming of Methane for Synthesis Gas Production Using the Tapered Element Oscillation Micro... | 249 |
10 Utilization of Carbon Dioxide through Nonthermal Plasma Approaches | 267 |
11 Photochemical Electrochemical and Photoelectrochemical Reduction of Carbon Dioxide | 291 |
12 Recent Scientific and Technological Developments in Electrochemical Carboxylation Based on Carbon Dioxide | 317 |
13 Indirect Utilization of Carbon Dioxide Utilization of Terrestrial and Aquatic Biomass | 335 |
14 Fixation of Carbon Dioxide into Inorganic Carbonates The Natural and Artificial Weathering of Silicates | 353 |
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acetyl-CoA acid activity alcohols aliphatic alkyl alkynes amines anion aquatic biomass aqueous Aresta atoms autotrophic biomass bond carbamate carbamic acid Carbon Dioxide carbon formation carboxylation carboxylic acids Catal catalyst catalytic system chemical chemistry citric acid cycle CO2 pressure CO2 reduction CO2 reforming complex compounds conversion coordination copolymer copolymerization cycle cyclic carbonate Dibenedetto discharge electrocarboxylation electrochemical electrodes energy enzymes epoxides Equation esters faradaic efficiency Figure fixation fuels Green Chem halides hydrocarbons hydrogen Inorg intermediate investigated isocyanate ligand mechanism methane methanol mineral molecules monomer obtained ofthe organic Organomet Organometallics overpotential oxetane oxidation oxygen Patent pathway phenoxide phosgene Phys polymer polymerization potential presence production react reactivity reactor reduce CO2 reduction of CO2 reported route RubisCO scCO2 Scheme selectivity solution solvent species studies substrate succinyl-CoA supercritical syngas synthesis technologies temperature Tetrahedron Lett tion transesterification urea versus SCE Wang yield Zevenhoven Zhang