Electrochemical Methods: Fundamentals and ApplicationsWiley, 2 set 1980 - 736 pagine Takes the student from the most basic chemical and physical principles through fundamentals of thermodynamics, kinetics, and mass transfer, to a thorough treatment of all important experimental methods. Treats application of electrochemical methods to elucidation of reaction mechanisms; double layer structure and surface processes, and their effects on electrode processes are developed from first principles; other key features include a chapter on operational amplifier circuits and electrochemical instrumentation, unique coverage of spectrometric and photochemical experiments, and Laplace transform and digital simulation techniques. Contains numerous examples, illustrations, end-of-chapter problems, references, uniform mathematical notation, and an extensive list of symbols, abbreviations, definitions, and dimensions. |
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Pagina 30
... anodic limiting current , i , a , when CR ( x = 0 ) ≈ 0. We still have Co ( x = 0 ) from ( 1.4.11 ) , with i , now specified as ic . The limiting anodic current naturally reflects the maximum rate at which R can be brought to the ...
... anodic limiting current , i , a , when CR ( x = 0 ) ≈ 0. We still have Co ( x = 0 ) from ( 1.4.11 ) , with i , now specified as ic . The limiting anodic current naturally reflects the maximum rate at which R can be brought to the ...
Pagina 229
... anodic scan is virtually the same as that which would result from an initial anodic scan in a solution containing only R. Deviation of the ratio ipa / ipe from unity is indicative of kinetic or other complications in the electrode ...
... anodic scan is virtually the same as that which would result from an initial anodic scan in a solution containing only R. Deviation of the ratio ipa / ipe from unity is indicative of kinetic or other complications in the electrode ...
Pagina 392
... anodic wave for Fe2 + oxidation is observed . During the titration ( 0 < ƒ < 1 ) the solution contains Fe2 + , Fe3 + , and Ce3 + , while after the equivalence point ( f > 1 ) the solution contains Fe3 + , Ce3 + , and Ce1 + . The ...
... anodic wave for Fe2 + oxidation is observed . During the titration ( 0 < ƒ < 1 ) the solution contains Fe2 + , Fe3 + , and Ce3 + , while after the equivalence point ( f > 1 ) the solution contains Fe3 + , Ce3 + , and Ce1 + . The ...
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Electrochemical Methods: Fundamentals and Applications Allen J. Bard,Larry R. Faulkner Visualizzazione estratti - 1980 |
Parole e frasi comuni
A. J. Bard adsorbed adsorption American Chemical Society Anal anodic anthracene applied behavior bulk capacitance cathodic cell charge transfer Chem circuit cm/sec cm² Co(x coefficient complex components consider coulometric current-potential cyclic cyclic voltammetry derived diffusion layer disk double-layer drop E₁ effects electroactive electrochemical electrochemical cell Electrochemistry electrode potential electrode processes electrode reaction electrode surface electrolysis electron transfer equation equilibrium example experiment experimental faradaic free energy frequency function hence i-E curve impedance interface involving kinetic limiting current linear mass transfer measurements metal methods n-type semiconductor Nernst equation nernstian obtained overpotential oxidation parameters peak phase platinum plot polarography potential step potentiostat problem pulse R₁ rate constant redox reduction reference electrode Reprinted with permission reversible scan Section semiconductor shown in Figure simulation solution species techniques titration totally irreversible transform usually voltage voltammetry voltammogram wave zero