Electrochemical Methods: Fundamentals and ApplicationsWiley, 2 set 1980 - 736 pagine Takes the student from the most basic chemical and physical principles through fundamentals of thermodynamics, kinetics, and mass transfer, to a thorough treatment of all important experimental methods. Treats application of electrochemical methods to elucidation of reaction mechanisms; double layer structure and surface processes, and their effects on electrode processes are developed from first principles; other key features include a chapter on operational amplifier circuits and electrochemical instrumentation, unique coverage of spectrometric and photochemical experiments, and Laplace transform and digital simulation techniques. Contains numerous examples, illustrations, end-of-chapter problems, references, uniform mathematical notation, and an extensive list of symbols, abbreviations, definitions, and dimensions. |
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Pagina 443
... behavior of this system depends on the magnitudes of both the first - order rate constants , k , and k , ( sec - 1 ) , and the equilibrium constant , K. The relevant dimen- sionless parameters , A , for the different techniques for this ...
... behavior of this system depends on the magnitudes of both the first - order rate constants , k , and k , ( sec - 1 ) , and the equilibrium constant , K. The relevant dimen- sionless parameters , A , for the different techniques for this ...
Pagina 450
... behavior in chronoamperometric and polarographic methods will not be perturbed by irreversibility in the electron transfer reaction ; since the potential is stepped to a value sufficiently beyond the equilibrium value that reaction ...
... behavior in chronoamperometric and polarographic methods will not be perturbed by irreversibility in the electron transfer reaction ; since the potential is stepped to a value sufficiently beyond the equilibrium value that reaction ...
Pagina 461
... behavior in KP region . 11.3.6 ECE , Reactions We consider here only the case O1 + n1e R1 E k R1 O2 O2 + n2e R2 R2 E2 ( 11.3.37 ) ( 11.3.38 ) ( 11.3.39 ) ≥ where E2 >> Ei ( i.e. , where Eg - Ei 180 mV ) and only a single voltammetric ...
... behavior in KP region . 11.3.6 ECE , Reactions We consider here only the case O1 + n1e R1 E k R1 O2 O2 + n2e R2 R2 E2 ( 11.3.37 ) ( 11.3.38 ) ( 11.3.39 ) ≥ where E2 >> Ei ( i.e. , where Eg - Ei 180 mV ) and only a single voltammetric ...
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Electrochemical Methods: Fundamentals and Applications Allen J. Bard,Larry R. Faulkner Visualizzazione estratti - 1980 |
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A. J. Bard adsorbed adsorption American Chemical Society Anal anodic anthracene applied behavior bulk capacitance cathodic cell charge transfer Chem circuit cm/sec cm² Co(x coefficient complex components consider coulometric current-potential cyclic cyclic voltammetry derived diffusion layer disk double-layer drop E₁ effects electroactive electrochemical electrochemical cell Electrochemistry electrode potential electrode processes electrode reaction electrode surface electrolysis electron transfer equation equilibrium example experiment experimental faradaic free energy frequency function hence i-E curve impedance interface involving kinetic limiting current linear mass transfer measurements metal methods n-type semiconductor Nernst equation nernstian obtained overpotential oxidation parameters peak phase platinum plot polarography potential step potentiostat problem pulse R₁ rate constant redox reduction reference electrode Reprinted with permission reversible scan Section semiconductor shown in Figure simulation solution species techniques titration totally irreversible transform usually voltage voltammetry voltammogram wave zero