Electrochemical Methods: Fundamentals and ApplicationsWiley, 2 set 1980 - 736 pagine Takes the student from the most basic chemical and physical principles through fundamentals of thermodynamics, kinetics, and mass transfer, to a thorough treatment of all important experimental methods. Treats application of electrochemical methods to elucidation of reaction mechanisms; double layer structure and surface processes, and their effects on electrode processes are developed from first principles; other key features include a chapter on operational amplifier circuits and electrochemical instrumentation, unique coverage of spectrometric and photochemical experiments, and Laplace transform and digital simulation techniques. Contains numerous examples, illustrations, end-of-chapter problems, references, uniform mathematical notation, and an extensive list of symbols, abbreviations, definitions, and dimensions. |
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Risultati 1-3 di 55
Pagina xi
... cm sec - 1 -2 1.4.1 , 4.1 jo K k k ко ( b ) box index in a simulation ( c ) V - 1 exchange current density ... cm / sec 3.2 , 3.3 constant ko ( a ) heterogeneous rate constant for cm / sec 3.2 oxidation ( b ) homogeneous rate constant ...
... cm sec - 1 -2 1.4.1 , 4.1 jo K k k ко ( b ) box index in a simulation ( c ) V - 1 exchange current density ... cm / sec 3.2 , 3.3 constant ko ( a ) heterogeneous rate constant for cm / sec 3.2 oxidation ( b ) homogeneous rate constant ...
Pagina xiii
... cm 5.2.2 spherical electrode ( b ) radial distance from the axis of rotation cm 8.3.1 of a rotating electrode ro r1 ... sec དཅ ེ ནཁུ ། transit time at an RRDE sec transference number of species j none 8.5.2 2.3.3 , 4.1 known ...
... cm 5.2.2 spherical electrode ( b ) radial distance from the axis of rotation cm 8.3.1 of a rotating electrode ro r1 ... sec དཅ ེ ནཁུ ། transit time at an RRDE sec transference number of species j none 8.5.2 2.3.3 , 4.1 known ...
Pagina 227
... cm / sec Quasi - reversible 15 ≥ A ≥ 10−2 ( 1 + α ) ; 0.3v1 / 2 ≥ ko ≥ 2 × 10−5,1 / 2 cm / sec Totally irreversible A≤ 10-2 ( 1 + α ) ; k ° ≤ 2 × 10-5,1 / 2 cm / sec 6.5 REVERSAL TECHNIQUES Reversal techniques with linear scan ...
... cm / sec Quasi - reversible 15 ≥ A ≥ 10−2 ( 1 + α ) ; 0.3v1 / 2 ≥ ko ≥ 2 × 10−5,1 / 2 cm / sec Totally irreversible A≤ 10-2 ( 1 + α ) ; k ° ≤ 2 × 10-5,1 / 2 cm / sec 6.5 REVERSAL TECHNIQUES Reversal techniques with linear scan ...
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Electrochemical Methods: Fundamentals and Applications Allen J. Bard,Larry R. Faulkner Visualizzazione estratti - 1980 |
Parole e frasi comuni
A. J. Bard adsorbed adsorption American Chemical Society Anal anodic anthracene applied behavior bulk capacitance cathodic cell charge transfer Chem circuit cm/sec cm² Co(x coefficient complex components consider coulometric current-potential cyclic cyclic voltammetry derived diffusion layer disk double-layer drop E₁ effects electroactive electrochemical electrochemical cell Electrochemistry electrode potential electrode processes electrode reaction electrode surface electrolysis electron transfer equation equilibrium example experiment experimental faradaic free energy frequency function hence i-E curve impedance interface involving kinetic limiting current linear mass transfer measurements metal methods n-type semiconductor Nernst equation nernstian obtained overpotential oxidation parameters peak phase platinum plot polarography potential step potentiostat problem pulse R₁ rate constant redox reduction reference electrode Reprinted with permission reversible scan Section semiconductor shown in Figure simulation solution species techniques titration totally irreversible transform usually voltage voltammetry voltammogram wave zero