Electrochemical Methods: Fundamentals and ApplicationsWiley, 2 set 1980 - 736 pagine Takes the student from the most basic chemical and physical principles through fundamentals of thermodynamics, kinetics, and mass transfer, to a thorough treatment of all important experimental methods. Treats application of electrochemical methods to elucidation of reaction mechanisms; double layer structure and surface processes, and their effects on electrode processes are developed from first principles; other key features include a chapter on operational amplifier circuits and electrochemical instrumentation, unique coverage of spectrometric and photochemical experiments, and Laplace transform and digital simulation techniques. Contains numerous examples, illustrations, end-of-chapter problems, references, uniform mathematical notation, and an extensive list of symbols, abbreviations, definitions, and dimensions. |
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Pagina 53
... considering the thermodynamic points of the previous section , we were not required to advance a mechanistic basis for ... consider two prior questions : ( 1 ) Can we expect the potential within a phase to be uniform ? ( 2 ) If so , what ...
... considering the thermodynamic points of the previous section , we were not required to advance a mechanistic basis for ... consider two prior questions : ( 1 ) Can we expect the potential within a phase to be uniform ? ( 2 ) If so , what ...
Pagina 135
... Consider the electrolysis of a 0.10 M NaOH solution at platinum electrodes , where the reactions are : ( anode ) 2 20H ̄ → 102 + H2O + 2e ( cathode ) 2H2O + 2e → H2 + 2OH- Show the balance sheet for the system operating at steady ...
... Consider the electrolysis of a 0.10 M NaOH solution at platinum electrodes , where the reactions are : ( anode ) 2 20H ̄ → 102 + H2O + 2e ( cathode ) 2H2O + 2e → H2 + 2OH- Show the balance sheet for the system operating at steady ...
Pagina 147
... consider here the current that flows during a single lifetime when the DME is held at a potential in the mass - transfer - controlled region for electrolysis . That is , we seek the diffusion - limited current . The problem has been ...
... consider here the current that flows during a single lifetime when the DME is held at a potential in the mass - transfer - controlled region for electrolysis . That is , we seek the diffusion - limited current . The problem has been ...
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Electrochemical Methods: Fundamentals and Applications Allen J. Bard,Larry R. Faulkner Visualizzazione estratti - 1980 |
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A. J. Bard adsorbed adsorption American Chemical Society Anal anodic anthracene applied behavior bulk capacitance cathodic cell charge transfer Chem circuit cm/sec cm² Co(x coefficient complex components consider coulometric current-potential cyclic cyclic voltammetry derived diffusion layer disk double-layer drop E₁ effects electroactive electrochemical electrochemical cell Electrochemistry electrode potential electrode processes electrode reaction electrode surface electrolysis electron transfer equation equilibrium example experiment experimental faradaic free energy frequency function hence i-E curve impedance interface involving kinetic limiting current linear mass transfer measurements metal methods n-type semiconductor Nernst equation nernstian obtained overpotential oxidation parameters peak phase platinum plot polarography potential step potentiostat problem pulse R₁ rate constant redox reduction reference electrode Reprinted with permission reversible scan Section semiconductor shown in Figure simulation solution species techniques titration totally irreversible transform usually voltage voltammetry voltammogram wave zero