Electrochemical Methods: Fundamentals and ApplicationsWiley, 2 set 1980 - 736 pagine Takes the student from the most basic chemical and physical principles through fundamentals of thermodynamics, kinetics, and mass transfer, to a thorough treatment of all important experimental methods. Treats application of electrochemical methods to elucidation of reaction mechanisms; double layer structure and surface processes, and their effects on electrode processes are developed from first principles; other key features include a chapter on operational amplifier circuits and electrochemical instrumentation, unique coverage of spectrometric and photochemical experiments, and Laplace transform and digital simulation techniques. Contains numerous examples, illustrations, end-of-chapter problems, references, uniform mathematical notation, and an extensive list of symbols, abbreviations, definitions, and dimensions. |
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Pagina 33
... diffusion layer either in a stirred solution or in an unstirred solution where the diffusion layer continues to grow with time . Consider what hap- pens when a potential step of magnitude E is applied to an electrode immersed in a ...
... diffusion layer either in a stirred solution or in an unstirred solution where the diffusion layer continues to grow with time . Consider what hap- pens when a potential step of magnitude E is applied to an electrode immersed in a ...
Pagina 505
... diffusion layers for faradaic experiments . It becomes thicker as the concentration of electrolyte falls , as we anticipated in the qualitative discussion above . ( b ) The ... Diffuse Layer C * 12.3 Models for Double - Layer Structure 505.
... diffusion layers for faradaic experiments . It becomes thicker as the concentration of electrolyte falls , as we anticipated in the qualitative discussion above . ( b ) The ... Diffuse Layer C * 12.3 Models for Double - Layer Structure 505.
Pagina 708
... Diffusion coefficient , 129 , 677,678 , 683 in digital simulation , 678 ... layer : thickness , 28 , 129 , 683 RDE , 288 treatment of convective systems ... layer : charge density , 8 , 9 diffuse , see Diffuse layer effect on electrode ...
... Diffusion coefficient , 129 , 677,678 , 683 in digital simulation , 678 ... layer : thickness , 28 , 129 , 683 RDE , 288 treatment of convective systems ... layer : charge density , 8 , 9 diffuse , see Diffuse layer effect on electrode ...
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Electrochemical Methods: Fundamentals and Applications Allen J. Bard,Larry R. Faulkner Visualizzazione estratti - 1980 |
Parole e frasi comuni
A. J. Bard adsorbed adsorption American Chemical Society Anal anodic anthracene applied behavior bulk capacitance cathodic cell charge transfer Chem circuit cm/sec cm² Co(x coefficient complex components consider coulometric current-potential cyclic cyclic voltammetry derived diffusion layer disk double-layer drop E₁ effects electroactive electrochemical electrochemical cell Electrochemistry electrode potential electrode processes electrode reaction electrode surface electrolysis electron transfer equation equilibrium example experiment experimental faradaic free energy frequency function hence i-E curve impedance interface involving kinetic limiting current linear mass transfer measurements metal methods n-type semiconductor Nernst equation nernstian obtained overpotential oxidation parameters peak phase platinum plot polarography potential step potentiostat problem pulse R₁ rate constant redox reduction reference electrode Reprinted with permission reversible scan Section semiconductor shown in Figure simulation solution species techniques titration totally irreversible transform usually voltage voltammetry voltammogram wave zero