Electrochemical Methods: Fundamentals and ApplicationsWiley, 2 set 1980 - 736 pagine Takes the student from the most basic chemical and physical principles through fundamentals of thermodynamics, kinetics, and mass transfer, to a thorough treatment of all important experimental methods. Treats application of electrochemical methods to elucidation of reaction mechanisms; double layer structure and surface processes, and their effects on electrode processes are developed from first principles; other key features include a chapter on operational amplifier circuits and electrochemical instrumentation, unique coverage of spectrometric and photochemical experiments, and Laplace transform and digital simulation techniques. Contains numerous examples, illustrations, end-of-chapter problems, references, uniform mathematical notation, and an extensive list of symbols, abbreviations, definitions, and dimensions. |
Dall'interno del libro
Risultati 1-3 di 91
Pagina 62
... equilibrium , and we have learned that the potential differences in equilibrium electrochemical systems can be treated exactly by thermodynamics . However , many real cells are never at equilibrium be- cause they feature different ...
... equilibrium , and we have learned that the potential differences in equilibrium electrochemical systems can be treated exactly by thermodynamics . However , many real cells are never at equilibrium be- cause they feature different ...
Pagina 87
... equilibrium , the net conversion rate is zero ; hence k , ko CB = K = CA ( 3.1.5 ) The kinetic theory therefore predicts a constant concentration ratio at equilibrium , just as thermodynamics does . Such agreement is required of any ...
... equilibrium , the net conversion rate is zero ; hence k , ko CB = K = CA ( 3.1.5 ) The kinetic theory therefore predicts a constant concentration ratio at equilibrium , just as thermodynamics does . Such agreement is required of any ...
Pagina 91
... equilibrium , it will hold away from equilibrium . The assumption of equilibrium , though useful in the derivation , does not constrain the equation's range of validity . 3.2 ESSENTIALS OF ELECTRODE REACTIONS ( 4-12 ) We noted above ...
... equilibrium , it will hold away from equilibrium . The assumption of equilibrium , though useful in the derivation , does not constrain the equation's range of validity . 3.2 ESSENTIALS OF ELECTRODE REACTIONS ( 4-12 ) We noted above ...
Altre edizioni - Visualizza tutto
Electrochemical Methods: Fundamentals and Applications Allen J. Bard,Larry R. Faulkner Visualizzazione estratti - 1980 |
Parole e frasi comuni
A. J. Bard adsorbed adsorption American Chemical Society Anal anodic anthracene applied behavior bulk capacitance cathodic cell charge transfer Chem circuit cm/sec cm² Co(x coefficient complex components consider coulometric current-potential cyclic cyclic voltammetry derived diffusion layer disk double-layer drop E₁ effects electroactive electrochemical electrochemical cell Electrochemistry electrode potential electrode processes electrode reaction electrode surface electrolysis electron transfer equation equilibrium example experiment experimental faradaic free energy frequency function hence i-E curve impedance interface involving kinetic limiting current linear mass transfer measurements metal methods n-type semiconductor Nernst equation nernstian obtained overpotential oxidation parameters peak phase platinum plot polarography potential step potentiostat problem pulse R₁ rate constant redox reduction reference electrode Reprinted with permission reversible scan Section semiconductor shown in Figure simulation solution species techniques titration totally irreversible transform usually voltage voltammetry voltammogram wave zero