Electrochemical Methods: Fundamentals and ApplicationsWiley, 2 set 1980 - 736 pagine Takes the student from the most basic chemical and physical principles through fundamentals of thermodynamics, kinetics, and mass transfer, to a thorough treatment of all important experimental methods. Treats application of electrochemical methods to elucidation of reaction mechanisms; double layer structure and surface processes, and their effects on electrode processes are developed from first principles; other key features include a chapter on operational amplifier circuits and electrochemical instrumentation, unique coverage of spectrometric and photochemical experiments, and Laplace transform and digital simulation techniques. Contains numerous examples, illustrations, end-of-chapter problems, references, uniform mathematical notation, and an extensive list of symbols, abbreviations, definitions, and dimensions. |
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Pagina 53
... hence a system like might be preferred . Ag / Ag + ( 0.01 M in CH3CN ) ( 2.1.43 ) Since the potential of a reference electrode vs. NHE or SCE is nearly always speci- fied in experimental papers , interconversion of scales can be ...
... hence a system like might be preferred . Ag / Ag + ( 0.01 M in CH3CN ) ( 2.1.43 ) Since the potential of a reference electrode vs. NHE or SCE is nearly always speci- fied in experimental papers , interconversion of scales can be ...
Pagina 200
... hence the later parts of the transient , which are most accessible experimentally and are least distorted by nonideal potential rise , offer better signal - to - noise ratios than the early time results . The opposite is true for ...
... hence the later parts of the transient , which are most accessible experimentally and are least distorted by nonideal potential rise , offer better signal - to - noise ratios than the early time results . The opposite is true for ...
Pagina 330
... hence σ and Z , must be large . Current response to Éac is not very great , because the supply of one reagent is insufficient to permit a high reaction rate for the cyclic , reversible electrode process that causes the ac current ...
... hence σ and Z , must be large . Current response to Éac is not very great , because the supply of one reagent is insufficient to permit a high reaction rate for the cyclic , reversible electrode process that causes the ac current ...
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Electrochemical Methods: Fundamentals and Applications Allen J. Bard,Larry R. Faulkner Visualizzazione estratti - 1980 |
Parole e frasi comuni
A. J. Bard adsorbed adsorption American Chemical Society Anal anodic anthracene applied behavior bulk capacitance cathodic cell charge transfer Chem circuit cm/sec cm² Co(x coefficient complex components consider coulometric current-potential cyclic cyclic voltammetry derived diffusion layer disk double-layer drop E₁ effects electroactive electrochemical electrochemical cell Electrochemistry electrode potential electrode processes electrode reaction electrode surface electrolysis electron transfer equation equilibrium example experiment experimental faradaic free energy frequency function hence i-E curve impedance interface involving kinetic limiting current linear mass transfer measurements metal methods n-type semiconductor Nernst equation nernstian obtained overpotential oxidation parameters peak phase platinum plot polarography potential step potentiostat problem pulse R₁ rate constant redox reduction reference electrode Reprinted with permission reversible scan Section semiconductor shown in Figure simulation solution species techniques titration totally irreversible transform usually voltage voltammetry voltammogram wave zero