Electrochemical Methods: Fundamentals and ApplicationsWiley, 2 set 1980 - 736 pagine Takes the student from the most basic chemical and physical principles through fundamentals of thermodynamics, kinetics, and mass transfer, to a thorough treatment of all important experimental methods. Treats application of electrochemical methods to elucidation of reaction mechanisms; double layer structure and surface processes, and their effects on electrode processes are developed from first principles; other key features include a chapter on operational amplifier circuits and electrochemical instrumentation, unique coverage of spectrometric and photochemical experiments, and Laplace transform and digital simulation techniques. Contains numerous examples, illustrations, end-of-chapter problems, references, uniform mathematical notation, and an extensive list of symbols, abbreviations, definitions, and dimensions. |
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Pagina 7
... metal ions , oxygen , and organic species ) , and in clean systems this current is quite small . 1.2.2 Capacitance and Charge of an Electrode Since charge cannot cross ... Metal Solution Metal Solution ( a ) + + + 1.2 Nonfaradaic Processes 7.
... metal ions , oxygen , and organic species ) , and in clean systems this current is quite small . 1.2.2 Capacitance and Charge of an Electrode Since charge cannot cross ... Metal Solution Metal Solution ( a ) + + + 1.2 Nonfaradaic Processes 7.
Pagina 8
Fundamentals and Applications Allen J. Bard, Larry R. Faulkner. Metal Solution Metal Solution ( a ) + + + + + + ( b ) Figure 1.2.2 The metal - solution interface as a capacitor with a charge on the metal , q , ( a ) negative and ( b ) ...
Fundamentals and Applications Allen J. Bard, Larry R. Faulkner. Metal Solution Metal Solution ( a ) + + + + + + ( b ) Figure 1.2.2 The metal - solution interface as a capacitor with a charge on the metal , q , ( a ) negative and ( b ) ...
Pagina 55
... metal sphere surrounded by an uncharged electrolyte . We know that the charge on the metal qM resides on its surface . This unbalanced charge ( negative in the diagram ) will create an excess cation concentration near the electrode in ...
... metal sphere surrounded by an uncharged electrolyte . We know that the charge on the metal qM resides on its surface . This unbalanced charge ( negative in the diagram ) will create an excess cation concentration near the electrode in ...
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Electrochemical Methods: Fundamentals and Applications Allen J. Bard,Larry R. Faulkner Visualizzazione estratti - 1980 |
Parole e frasi comuni
A. J. Bard adsorbed adsorption American Chemical Society Anal anodic anthracene applied behavior bulk capacitance cathodic cell charge transfer Chem circuit cm/sec cm² Co(x coefficient complex components consider coulometric current-potential cyclic cyclic voltammetry derived diffusion layer disk double-layer drop E₁ effects electroactive electrochemical electrochemical cell Electrochemistry electrode potential electrode processes electrode reaction electrode surface electrolysis electron transfer equation equilibrium example experiment experimental faradaic free energy frequency function hence i-E curve impedance interface involving kinetic limiting current linear mass transfer measurements metal methods n-type semiconductor Nernst equation nernstian obtained overpotential oxidation parameters peak phase platinum plot polarography potential step potentiostat problem pulse R₁ rate constant redox reduction reference electrode Reprinted with permission reversible scan Section semiconductor shown in Figure simulation solution species techniques titration totally irreversible transform usually voltage voltammetry voltammogram wave zero