## Electrochemical Methods: Fundamentals and ApplicationsTakes the student from the most basic chemical and physical principles through fundamentals of thermodynamics, kinetics, and mass transfer, to a thorough treatment of all important experimental methods. Treats application of electrochemical methods to elucidation of reaction mechanisms; double layer structure and surface processes, and their effects on electrode processes are developed from first principles; other key features include a chapter on operational amplifier circuits and electrochemical instrumentation, unique coverage of spectrometric and photochemical experiments, and Laplace transform and digital simulation techniques. Contains numerous examples, illustrations, end-of-chapter problems, references, uniform mathematical notation, and an extensive list of symbols, abbreviations, definitions, and dimensions. |

### Dall'interno del libro

Risultati 1-3 di 78

Pagina 217

A closed-form solution of (6.2.1 1) cannot be

must be employed. Before solving (6.2.11) numerically, it is convenient (a) to

change from /(f) to i(E), since that is the way in which the data are usually

considered, ...

A closed-form solution of (6.2.1 1) cannot be

**obtained**, and a numerical methodmust be employed. Before solving (6.2.11) numerically, it is convenient (a) to

change from /(f) to i(E), since that is the way in which the data are usually

considered, ...

Pagina 253

By substitution of the known function, i(s), and employing the inverse transform,

C0(x, t) can be

derived : Note that direct inversion of (7.2.8) and (7.2.9) using the convolution ...

By substitution of the known function, i(s), and employing the inverse transform,

C0(x, t) can be

**obtained**. Similarly, the following expression for CR(x, s) can bederived : Note that direct inversion of (7.2.8) and (7.2.9) using the convolution ...

Pagina 295

Note that as p-+ao (i.e., high solution resistance and small RE), the current

distribution approaches the primary one. Conversely, for small values of p (highly

conductive solutions and large RE) a fairly uniform current distribution is

.

Note that as p-+ao (i.e., high solution resistance and small RE), the current

distribution approaches the primary one. Conversely, for small values of p (highly

conductive solutions and large RE) a fairly uniform current distribution is

**obtained**.

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Electrochemical methods: fundamentals and applications Allen J. Bard,Larry R. Faulkner Visualizzazione frammento - 1980 |

### Parole e frasi comuni

A. J. Bard adsorbed adsorption American Chemical Society Anal anodic anthracene applied behavior boundary conditions bulk capacitance cathodic cell cell potential charge transfer Chem circuit cm/sec coefficient complex components consider coulometric current-potential cyclic cyclic voltammetry density derived differential diffusion layer disk double-layer drop effect electrochemical electrochemical cell Electrochemistry electrode potential electrode processes electrode reaction electrode surface electrolysis electron transfer equation equilibrium example experiment experimental faradaic free energy frequency function given hence i-E curve impedance interface involving kinetic limiting current linear mass transfer measurements metal methods Nernst equation nernstian obtained overpotential oxidation parameters peak Phys platinum plot polarography potential step potentiostat problem pulse rate constant redox reduction reference electrode region Reprinted with permission reversible RRDE Section semiconductor shown in Figure simulation solution surface concentrations techniques titration totally irreversible transfer reaction transform treatment usually voltage voltammetry voltammogram wave yields zero