Electrochemical Methods: Fundamentals and ApplicationsWiley, 2 set 1980 - 736 pagine Takes the student from the most basic chemical and physical principles through fundamentals of thermodynamics, kinetics, and mass transfer, to a thorough treatment of all important experimental methods. Treats application of electrochemical methods to elucidation of reaction mechanisms; double layer structure and surface processes, and their effects on electrode processes are developed from first principles; other key features include a chapter on operational amplifier circuits and electrochemical instrumentation, unique coverage of spectrometric and photochemical experiments, and Laplace transform and digital simulation techniques. Contains numerous examples, illustrations, end-of-chapter problems, references, uniform mathematical notation, and an extensive list of symbols, abbreviations, definitions, and dimensions. |
Dall'interno del libro
Risultati 1-3 di 64
Pagina 94
... oxidation is lowered , the net transformation is conversion of Na ( Hg ) to Na + + e . Setting the potential to a value more negative than Ee , raises the energy of the electron and shifts the curve for Na + + e to higher energies as ...
... oxidation is lowered , the net transformation is conversion of Na ( Hg ) to Na + + e . Setting the potential to a value more negative than Ee , raises the energy of the electron and shifts the curve for Na + + e to higher energies as ...
Pagina 388
... oxidation of Fe2 + falls below 100 % , the next process to occur is Ce3 + + e . The Ce1 + so produced is capable of oxidizing any Fe2 + remaining in the bulk solution by the fast reaction Ce ++ Fe2 + → Ce3 + + Fe3 + → Ce1 + ( 10.4.3 ) ...
... oxidation of Fe2 + falls below 100 % , the next process to occur is Ce3 + + e . The Ce1 + so produced is capable of oxidizing any Fe2 + remaining in the bulk solution by the fast reaction Ce ++ Fe2 + → Ce3 + + Fe3 + → Ce1 + ( 10.4.3 ) ...
Pagina 539
... oxide ) layer on platinum inhibits many oxidation processes ( e.g. , the oxidation of hydrogen , oxalic Oxygen Double- region layer Hydrogen region 60 60 region i 12.6 Effect of Adsorption of Electroinactive Species 539.
... oxide ) layer on platinum inhibits many oxidation processes ( e.g. , the oxidation of hydrogen , oxalic Oxygen Double- region layer Hydrogen region 60 60 region i 12.6 Effect of Adsorption of Electroinactive Species 539.
Altre edizioni - Visualizza tutto
Electrochemical Methods: Fundamentals and Applications Allen J. Bard,Larry R. Faulkner Visualizzazione estratti - 1980 |
Parole e frasi comuni
A. J. Bard adsorbed adsorption American Chemical Society Anal anodic anthracene applied behavior bulk capacitance cathodic cell charge transfer Chem circuit cm/sec cm² Co(x coefficient complex components consider coulometric current-potential cyclic cyclic voltammetry derived diffusion layer disk double-layer drop E₁ effects electroactive electrochemical electrochemical cell Electrochemistry electrode potential electrode processes electrode reaction electrode surface electrolysis electron transfer equation equilibrium example experiment experimental faradaic free energy frequency function hence i-E curve impedance interface involving kinetic limiting current linear mass transfer measurements metal methods n-type semiconductor Nernst equation nernstian obtained overpotential oxidation parameters peak phase platinum plot polarography potential step potentiostat problem pulse R₁ rate constant redox reduction reference electrode Reprinted with permission reversible scan Section semiconductor shown in Figure simulation solution species techniques titration totally irreversible transform usually voltage voltammetry voltammogram wave zero