Electrochemical Methods: Fundamentals and ApplicationsWiley, 2 set 1980 - 736 pagine Takes the student from the most basic chemical and physical principles through fundamentals of thermodynamics, kinetics, and mass transfer, to a thorough treatment of all important experimental methods. Treats application of electrochemical methods to elucidation of reaction mechanisms; double layer structure and surface processes, and their effects on electrode processes are developed from first principles; other key features include a chapter on operational amplifier circuits and electrochemical instrumentation, unique coverage of spectrometric and photochemical experiments, and Laplace transform and digital simulation techniques. Contains numerous examples, illustrations, end-of-chapter problems, references, uniform mathematical notation, and an extensive list of symbols, abbreviations, definitions, and dimensions. |
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Pagina 391
... titrated substance ( 27 , 28 ) . Coulometric titration methods have also been used in chromatographic detectors and for determination of homo- geneous reaction rates ( 29 ) . 10.5 ELECTROMETRIC END POINT DETECTION ( 30-35 ) 10.5.1 ...
... titrated substance ( 27 , 28 ) . Coulometric titration methods have also been used in chromatographic detectors and for determination of homo- geneous reaction rates ( 29 ) . 10.5 ELECTROMETRIC END POINT DETECTION ( 30-35 ) 10.5.1 ...
Pagina 395
... Titration curve for two - electrode potentiometric detection in the Fe2 + -Ce + titration . Two identical platinum electrodes with an impressed current i ic is assumed . ( See Figures 10.5.2 and 10.5.3 . ) lial = 10.5.4 Amperometric ...
... Titration curve for two - electrode potentiometric detection in the Fe2 + -Ce + titration . Two identical platinum electrodes with an impressed current i ic is assumed . ( See Figures 10.5.2 and 10.5.3 . ) lial = 10.5.4 Amperometric ...
Pagina 398
... titration curves ( potentiometric and amperometric ) that result for other different cases involving reversible and irreversible couples as titrants and titrates . The amperometric titration curves for coulometric titrations will have ...
... titration curves ( potentiometric and amperometric ) that result for other different cases involving reversible and irreversible couples as titrants and titrates . The amperometric titration curves for coulometric titrations will have ...
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Electrochemical Methods: Fundamentals and Applications Allen J. Bard,Larry R. Faulkner Visualizzazione estratti - 1980 |
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A. J. Bard adsorbed adsorption American Chemical Society Anal anodic anthracene applied behavior bulk capacitance cathodic cell charge transfer Chem circuit cm/sec cm² Co(x coefficient complex components consider coulometric current-potential cyclic cyclic voltammetry derived diffusion layer disk double-layer drop E₁ effects electroactive electrochemical electrochemical cell Electrochemistry electrode potential electrode processes electrode reaction electrode surface electrolysis electron transfer equation equilibrium example experiment experimental faradaic free energy frequency function hence i-E curve impedance interface involving kinetic limiting current linear mass transfer measurements metal methods n-type semiconductor Nernst equation nernstian obtained overpotential oxidation parameters peak phase platinum plot polarography potential step potentiostat problem pulse R₁ rate constant redox reduction reference electrode Reprinted with permission reversible scan Section semiconductor shown in Figure simulation solution species techniques titration totally irreversible transform usually voltage voltammetry voltammogram wave zero