Electrochemical Constants: Proceedings of the NBS Semi-centennial Symposium on Electrochemical Constants Held at the NBS on Sept. 19-21, 1951U.S. Government Printing Office, 1953 - 310 pagine |
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Pagina 27
... plot they appear to approach the theoretical line tangentially . However , it should be noted that the deviations with which we are concerned at low concentration are of very small magnitude and can- not be seen clearly when plotted on ...
... plot they appear to approach the theoretical line tangentially . However , it should be noted that the deviations with which we are concerned at low concentration are of very small magnitude and can- not be seen clearly when plotted on ...
Pagina 28
... plot for potassium iodide is shown in figure 4.2 , where the deviations in A - units are plotted against values of C. It will be noted that the deviations below 1 × 10-3 N are negative , with a maximum deviation of 0.07 A - unit at ...
... plot for potassium iodide is shown in figure 4.2 , where the deviations in A - units are plotted against values of C. It will be noted that the deviations below 1 × 10-3 N are negative , with a maximum deviation of 0.07 A - unit at ...
Pagina 29
... plot of measured values of Ao ' . It remains to evaluate D. This is best done by graphical means . If we write B / D = n , we may write eq ( 2 ) in the form or Ao Ao + D ( n + log C ) C , = A + DC log C / C * . ( 7 ) ( 7 ' ) A plot of ...
... plot of measured values of Ao ' . It remains to evaluate D. This is best done by graphical means . If we write B / D = n , we may write eq ( 2 ) in the form or Ao Ao + D ( n + log C ) C , = A + DC log C / C * . ( 7 ) ( 7 ' ) A plot of ...
Pagina 30
... plot of Ao ' versus C , A , is found to be 145.12 by inter- polation . To find D , we plot values of Ao ' against values of C log A。= ( ^ + BVC ) / ( 1 - α√ē ) 145.2 145.1 2 5 145.0 -6 -5 -4 -3 -2 - | 104 xc log c / c * A。= 145.110 2 ...
... plot of Ao ' versus C , A , is found to be 145.12 by inter- polation . To find D , we plot values of Ao ' against values of C log A。= ( ^ + BVC ) / ( 1 - α√ē ) 145.2 145.1 2 5 145.0 -6 -5 -4 -3 -2 - | 104 xc log c / c * A。= 145.110 2 ...
Pagina 40
... plot against the difference between the con- centrations . What you are doing is simply plotting against the micelle concentration . That is standard practice , as a matter of fact , when you consider light scattering from soap ...
... plot against the difference between the con- centrations . What you are doing is simply plotting against the micelle concentration . That is standard practice , as a matter of fact , when you consider light scattering from soap ...
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Electrochemical Constants: Proceedings of the NBS Semi-centennial Symposium ... United States. National Bureau of Standards Visualizzazione completa - 1953 |
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absolute acid activity coefficient AgNO3 anode approximately aqueous solutions Bockris boundary Bureau of Standards calculated capillary cathode CdSO4 charge Chem chloride Clark cell conductance cork coulometer curves density deposit determined deviation dielectric constant diffusion coefficient double layer effect electrical electrochemical electrochemical potential electrolyte electromotive force equation equivalent experimental experiments faraday function galvanic cell glass gradient H. S. Harned H₂ Hamer Harned and Owen heat of transfer hydrogen hysteresis Ilkovic increase ionization ions linear measurements metal methanol method molal molal volumes NaCl National Bureau observed obtained Onsager OVERBEEK overpotential overvoltage oxidation partial molal percent Phys plot polarization potassium potential difference reaction References salt saturated septa shown in figure shows silver sodium oxalate solid solvent Soret coefficient standard cells sulfate surface t-butanol temperature theory thermodynamic tion transference number tube values Vinal voltage Volts weight zero