Fundamentals of ElectrochemistryPlenum, 1993 - 589 pagine A rigorous outline of the basic concepts (phenomena, processes, laws) forming the subject matter of modern theoretical and applied electrochemistry, originally published in Russian in 1988 by Khimiya Press, Moscow. In the present English edition three supplementary chapters have been added, on photo |
Sommario
Electric Current in Galvanic Cells | 3 |
Aqueous Electrolyte Solutions | 10 |
Electrode Potentials | 29 |
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according to Eq acid adsorbed adsorption anions anodic anodic reaction aqueous solutions atoms calculated capacitance cathodic cathodic reaction cations charge chemical potential circuit components concentration gradients conductivity conductors constant convection corresponding current density current flow decrease depends determined dissociation effect elec electric electrochemical potential electrochemical reaction electrochemistry electrode potential electrode reaction electrode surface electrolyte solutions electrostatic equation equilibrium potential exchange cd experimental flux function Galvani potential galvanic cell galvanostatic Gibbs energy Hence hydrogen evolution increase interaction interface ionic ionic atmosphere ions kinetic lattice liquid measured membrane mercury metal molecules negative Nernst equation oxidation oxygen oxygen evolution parameters particles phase platinum polarization curves positive potential difference processes reactant reaction occurs reaction rate redox reference electrode region Section semiconductor solvation solvent species step substances surface concentration surface layer temperature thermodynamic tion transfer transport numbers trode values of polarization voltage zero