Principles of Inorganic Chemistry

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John Wiley & Sons, 24 mar 2015 - 760 pagine
Aimed at senior undergraduates and first-year graduate students, this book offers a principles-based approach to inorganic chemistry that, unlike other texts, uses chemical applications of group theory and molecular orbital theory throughout as an underlying framework. This highly physical approach allows students to derive the greatest benefit of topics such as molecular orbital acid-base theory, band theory of solids, and inorganic photochemistry, to name a few.

  • Takes a principles-based, group and molecular orbital theory approach to inorganic chemistry
  • The first inorganic chemistry textbook to provide a thorough treatment of group theory, a topic usually relegated to only one or two chapters of texts, giving it only a cursory overview
  • Covers atomic and molecular term symbols, symmetry coordinates in vibrational spectroscopy using the projection operator method, polyatomic MO theory, band theory, and Tanabe-Sugano diagrams
  • Includes a heavy dose of group theory in the primary inorganic textbook, most of the pedagogical benefits of integration and reinforcement of this material in the treatment of other topics, such as frontier MO acid--base theory, band theory of solids, inorganic photochemistry, the Jahn-Teller effect, and Wade's rules are fully realized
  • Very physical in nature compare to other textbooks in the field, taking the time to go through mathematical derivations and to compare and contrast different theories of bonding in order to allow for a more rigorous treatment of their application to molecular structure, bonding, and spectroscopy
  • Informal and engaging writing style; worked examples throughout the text; unanswered problems in every chapter; contains a generous use of informative, colorful illustrations
 

Sommario

Cover
Acknowledgments
8
13
8
9
2
1
1
1
EXERCISES
Molecular Geometry
Molecular Symmetry
List of Illustrations
1
1

14
The Structure of the Nucleus
8
1
9
1
18
1
2
A Brief Review of Quantum Theory
1
1
1
1
10
9
1
1
1
Atomic Structure
1
11
1
Periodic Properties of the Elements
1
1
1
Vibrational Spectroscopy
1
Covalent Bonding
1
1
Metallic Bonding
BONDING
DISCRETE MOLECULES
Ionic Bonding
1
2
Structure and Bonding
Structure and Reactivity
An Introduction to Coordination
GEOMETRIES
COORDINATION COMPOUNDS
Structure Bonding and Spectroscopy
Coordination Compounds
REACTIONS
Structure and Bonding in Organometallic
Reactions of Organometallic Compounds
Derivation of the Classical Wave Equation
Direct Product Tables
Correlation Tables

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Informazioni sull'autore (2015)

Brian W. Pfennig, PhD, received his undergraduate B.S. degree in chemistry at Albright College in 1988. He earned his Ph.D. in 1992 in the field of physical inorganic chemistry at Princeton University with Dr. Andrew B. Bocarsly, studying the photochemistry of organometallic sandwich compounds and electron transfer in multinuclear mixed-valence coordination compounds. Dr. Pfennig has held a number of different teaching appointments at small liberal arts colleges, including Franklin & Marshall College, Haverford College, Vassar College, and Ursinus College. During his 20-year teaching career, he has taught general chemistry, an accelerated one-semester general chemistry course, both introductory and advanced inorganic chemistry, bio-inorganic chemistry, and inorganic and organometallic photochemistry, as well as serving as the general chemistry laboratory coordinator at Ursinus College for the past 10 years. He is also actively engaged in research with undergraduates in the areas of inorganic photochemistry, electrochemistry, and electron transfer processes occurring in multinuclear mixed-valence coordination compounds. He has also published several papers in the area of chemical education.

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