Inorganic Electrochemistry: Theory, Practice and Applications

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Royal Society of Chemistry, 2003 - 615 pagine
Electrochemistry can be an elegant and essential support to synthetic inorganic chemistry. However, it is often perceived as a difficult technique. This book aims to introduce inorganic chemists to electrochemical investigations in as straightforward a way as possible. First, the reader is introduced to the theory of electron transfer processes, how they can be studied by various electrochemical techniques, and the practical procedures required. The book then goes on to look extensively, and with numerous illustrations, at the application of the techniques in the multiple fields of inorganic chemistry (including organometallics, coordination compounds, bioinorganics/biomimetics and materials science). Topics covered include: metallocenes; organometallic and coordination complexes; metal complexes of redox active ligands; metal-carbonyl clusters; superconductors; molecular wires; and proteins. Throughout, special attention is paid to the structural effects accompanying the electron transfer processes. This unique book bridges the gap between undergraduate and research-level electrochemistry books, and will be welcomed as an introduction to electrochemical applications within inorganic chemistry.
 

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Sommario

Introduction
1
Fundamentals of Electrode Reactions
7
Voltammetric Techniques
49
Basic Equipment for Electrochemical Measurements
139
The Electrochemical Behaviour of First
159
Dendrimers
185
Vanadocenes
204
Nickelocenes
210
Metal Complexes Containing Redoxactive Ligands
325
Electrochemically Induced Structural Modifications
381
from a Metal Centre to a Peripheral Ligand
397
Transition Metal Clusters
409
The Reactivity of Transition Metal Complexes
445
Superconductors in Electrochemistry
497
of Superconducting Materials
507
An Electrochemical
517

The Electrochemical Behaviour of Transition
217
in Photosynthesis
244
Iron Complexes
263
in Polynuclear Iron Complexes
274
Nickel Complexes
290
The Direct Electrochemistry of Redoxactive
539
Linear Correlations Between the Redox Potential
579
Appendices
603
Copyright

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Informazioni sull'autore (2003)

Piero Zanello is Head of the Department of Chemistry at the University of Siena since 1996.

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