Inorganic Electrochemistry: Theory, Practice and Applications

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Royal Society of Chemistry, 2003 - 615 pagine
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Electrochemistry can be an elegant and essential support to synthetic inorganic chemistry. However, it is often perceived as a difficult technique. This book aims to introduce inorganic chemists to electrochemical investigations in as straightforward a way as possible. First, the reader is introduced to the theory of electron transfer processes, how they can be studied by various electrochemical techniques, and the practical procedures required. The book then goes on to look extensively, and with numerous illustrations, at the application of the techniques in the multiple fields of inorganic chemistry (including organometallics, coordination compounds, bioinorganics/biomimetics and materials science). Topics covered include: metallocenes; organometallic and coordination complexes; metal complexes of redox active ligands; metal-carbonyl clusters; superconductors; molecular wires; and proteins. Throughout, special attention is paid to the structural effects accompanying the electron transfer processes. This unique book bridges the gap between undergraduate and research-level electrochemistry books, and will be welcomed as an introduction to electrochemical applications within inorganic chemistry.
 

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Indice

Introduction
1
Voltammetric Techniques
49
a Quasireversible Process
64
Basic Equipment for Electrochemical Measurements
139
The Electrochemical Behaviour of First
159
The Electrochemical Behaviour of Transition
217
185
324
Metal Complexes Containing Redoxactive Ligands
325
Carbonyl Clusters with Interstitial Atoms
432
The Reactivity of Transition Metal Complexes
445
Coordination to One Dinitrogen Molecule
476
Superconductors in Electrochemistry
497
of Superconducting Materials
507
An Electrochemical
517
The Direct Electrochemistry of Redoxactive
539
Linear Correlations Between the Redox Potential
579

Dithiolenes as Ligands in Metal Complexes
348
198
379
Electrochemically Induced Structural Modifications
381
Transition Metal Clusters
409
MoCO1s M Ru Os
427
204
583
Appendices
603
207
612
Copyright

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Informazioni sull'autore (2003)

Piero Zanello is Head of the Department of Chemistry at the University of Siena since 1996.

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