Electrochemical Methods: Fundamentals and ApplicationsWiley, 2 set 1980 - 736 pagine Takes the student from the most basic chemical and physical principles through fundamentals of thermodynamics, kinetics, and mass transfer, to a thorough treatment of all important experimental methods. Treats application of electrochemical methods to elucidation of reaction mechanisms; double layer structure and surface processes, and their effects on electrode processes are developed from first principles; other key features include a chapter on operational amplifier circuits and electrochemical instrumentation, unique coverage of spectrometric and photochemical experiments, and Laplace transform and digital simulation techniques. Contains numerous examples, illustrations, end-of-chapter problems, references, uniform mathematical notation, and an extensive list of symbols, abbreviations, definitions, and dimensions. |
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Pagina 515
... adsorption from aqueous solutions is often effective only at potentials relatively near the PZC . The usual rationale for this phenomenon rests on a recognition that adsorption of a neutral molecule requires the displacement of water ...
... adsorption from aqueous solutions is often effective only at potentials relatively near the PZC . The usual rationale for this phenomenon rests on a recognition that adsorption of a neutral molecule requires the displacement of water ...
Pagina 536
... adsorption of Cd ( II ) in the presence of SCN is an example of anion - induced adsorption , in which a specifically adsorbed substance ( e.g. , SCN , N3 , halide ion ) bonds to a metal ion in solution and thus promotes specific adsorption ...
... adsorption of Cd ( II ) in the presence of SCN is an example of anion - induced adsorption , in which a specifically adsorbed substance ( e.g. , SCN , N3 , halide ion ) bonds to a metal ion in solution and thus promotes specific adsorption ...
Pagina 538
... adsorbed and dissolved species , the behavior is more complex and depends on the form of the adsorption isotherm as well the manner in which the current divides between reduction of adsorbed and diffusing O. The problem is , in many ...
... adsorbed and dissolved species , the behavior is more complex and depends on the form of the adsorption isotherm as well the manner in which the current divides between reduction of adsorbed and diffusing O. The problem is , in many ...
Sommario
Potentials and Thermodynamics of Cells | 44 |
Kinetics of Electrode Reactions | 86 |
Mass Transfer by Migration and Diffusion | 119 |
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Electrochemical Methods: Fundamentals and Applications Allen J. Bard,Larry R. Faulkner Visualizzazione estratti - 1980 |
Parole e frasi comuni
A. J. Bard adsorbed adsorption American Chemical Society Anal anodic anthracene applied behavior bulk capacitance cathodic cell charge transfer Chem circuit cm/sec cm² Co(x coefficient components consider coulometric current-potential cyclic cyclic voltammetry density derived diffusion layer disk double-layer drop E₁ effect electroactive electrochemical electrochemical cell Electrochemistry electrode potential electrode processes electrode reaction electrode surface electrolysis electron transfer equation equilibrium example experiment experimental faradaic free energy frequency function hence i-E curve impedance interface involving kinetic limiting current linear mass transfer measurements metal methods n-type semiconductor Nernst equation nernstian obtained overpotential oxidation parameters peak phase platinum plot polarography potential step potentiostat problem pulse R₁ rate constant redox reduction reference electrode Reprinted with permission reversible scan Section semiconductor shown in Figure simulation solution species techniques titration totally irreversible usually voltage voltammetry voltammogram wave zero дх