Electrochemical Methods: Fundamentals and ApplicationsWiley, 2 set 1980 - 736 pagine Takes the student from the most basic chemical and physical principles through fundamentals of thermodynamics, kinetics, and mass transfer, to a thorough treatment of all important experimental methods. Treats application of electrochemical methods to elucidation of reaction mechanisms; double layer structure and surface processes, and their effects on electrode processes are developed from first principles; other key features include a chapter on operational amplifier circuits and electrochemical instrumentation, unique coverage of spectrometric and photochemical experiments, and Laplace transform and digital simulation techniques. Contains numerous examples, illustrations, end-of-chapter problems, references, uniform mathematical notation, and an extensive list of symbols, abbreviations, definitions, and dimensions. |
Dall'interno del libro
Risultati 1-3 di 85
Pagina 8
... double layer ( although its structure only very loosely resembles two charged layers , as we will see in Section 1.2.3 ) . At a given potential the electrode - solution interface is characterized by a double - layer capacitance , Ca ...
... double layer ( although its structure only very loosely resembles two charged layers , as we will see in Section 1.2.3 ) . At a given potential the electrode - solution interface is characterized by a double - layer capacitance , Ca ...
Pagina 9
... double - layer region . charged metal involves only long - range electrostatic forces , so that their interaction is ... layer , which extends from the OHP into the bulk of the solution . The excess charge density in the diffuse layer is ...
... double - layer region . charged metal involves only long - range electrostatic forces , so that their interaction is ... layer , which extends from the OHP into the bulk of the solution . The excess charge density in the diffuse layer is ...
Pagina 708
... Double layer : charge density , 8 , 9 diffuse , see Diffuse layer effect on electrode reaction , 9 effect on electrode reaction rate , 540 et seq . electrical , 56 definition , 8 models for , 500 et seq . potential profile , 9 , 504 ...
... Double layer : charge density , 8 , 9 diffuse , see Diffuse layer effect on electrode reaction , 9 effect on electrode reaction rate , 540 et seq . electrical , 56 definition , 8 models for , 500 et seq . potential profile , 9 , 504 ...
Sommario
Potentials and Thermodynamics of Cells | 44 |
Kinetics of Electrode Reactions | 86 |
Mass Transfer by Migration and Diffusion | 119 |
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Electrochemical Methods: Fundamentals and Applications Allen J. Bard,Larry R. Faulkner Visualizzazione estratti - 1980 |
Parole e frasi comuni
A. J. Bard adsorbed adsorption American Chemical Society Anal anodic anthracene applied behavior bulk capacitance cathodic cell charge transfer Chem circuit cm/sec cm² Co(x coefficient components consider coulometric current-potential cyclic cyclic voltammetry density derived diffusion layer disk double-layer drop E₁ effect electroactive electrochemical electrochemical cell Electrochemistry electrode potential electrode processes electrode reaction electrode surface electrolysis electron transfer equation equilibrium example experiment experimental faradaic free energy frequency function hence i-E curve impedance interface involving kinetic limiting current linear mass transfer measurements metal methods n-type semiconductor Nernst equation nernstian obtained overpotential oxidation parameters peak phase platinum plot polarography potential step potentiostat problem pulse R₁ rate constant redox reduction reference electrode Reprinted with permission reversible scan Section semiconductor shown in Figure simulation solution species techniques titration totally irreversible usually voltage voltammetry voltammogram wave zero дх