Electrochemical Methods: Fundamentals and ApplicationsWiley, 2 set 1980 - 736 pagine Takes the student from the most basic chemical and physical principles through fundamentals of thermodynamics, kinetics, and mass transfer, to a thorough treatment of all important experimental methods. Treats application of electrochemical methods to elucidation of reaction mechanisms; double layer structure and surface processes, and their effects on electrode processes are developed from first principles; other key features include a chapter on operational amplifier circuits and electrochemical instrumentation, unique coverage of spectrometric and photochemical experiments, and Laplace transform and digital simulation techniques. Contains numerous examples, illustrations, end-of-chapter problems, references, uniform mathematical notation, and an extensive list of symbols, abbreviations, definitions, and dimensions. |
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Pagina 237
... equation 6.7.1 becomes ( 15 ) where Co ( 0 , t ) = C * I ( t ) nFAD112 1 I ( t ) = 1/2 S i ( u ) - 0 du u ) 1/2 ( 6.7.2 ) ( 6.7.3 ) Following the generalized definition of the Riemann - Liouville operators , this integral can be ...
... equation 6.7.1 becomes ( 15 ) where Co ( 0 , t ) = C * I ( t ) nFAD112 1 I ( t ) = 1/2 S i ( u ) - 0 du u ) 1/2 ( 6.7.2 ) ( 6.7.3 ) Following the generalized definition of the Riemann - Liouville operators , this integral can be ...
Pagina 282
... equations . Before the convective - diffusion equation can be solved for the concentration profiles , C , ( x , y , z ) , and subsequently for the currents from the concentration gradients at the electrode surface , expressions for the ...
... equations . Before the convective - diffusion equation can be solved for the concentration profiles , C , ( x , y , z ) , and subsequently for the currents from the concentration gradients at the electrode surface , expressions for the ...
Pagina 713
... equation , 282 Nernst diffusion layer , 32 Nernst equation , 51 , 62 kinetic derivation of , 100 Nernst - Planck equation , 27 , 120 Nernstian reaction , definition , 29 Nernstian waves , 29 et seq . ac voltammetry , 331 et seq . , 342 ...
... equation , 282 Nernst diffusion layer , 32 Nernst equation , 51 , 62 kinetic derivation of , 100 Nernst - Planck equation , 27 , 120 Nernstian reaction , definition , 29 Nernstian waves , 29 et seq . ac voltammetry , 331 et seq . , 342 ...
Sommario
Potentials and Thermodynamics of Cells | 44 |
Kinetics of Electrode Reactions | 86 |
Mass Transfer by Migration and Diffusion | 119 |
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Electrochemical Methods: Fundamentals and Applications Allen J. Bard,Larry R. Faulkner Visualizzazione estratti - 1980 |
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A. J. Bard adsorbed adsorption American Chemical Society Anal anodic anthracene applied behavior bulk capacitance cathodic cell charge transfer Chem circuit cm/sec cm² Co(x coefficient components consider coulometric current-potential cyclic cyclic voltammetry density derived diffusion layer disk double-layer drop E₁ effect electroactive electrochemical electrochemical cell Electrochemistry electrode potential electrode processes electrode reaction electrode surface electrolysis electron transfer equation equilibrium example experiment experimental faradaic free energy frequency function hence i-E curve impedance interface involving kinetic limiting current linear mass transfer measurements metal methods n-type semiconductor Nernst equation nernstian obtained overpotential oxidation parameters peak phase platinum plot polarography potential step potentiostat problem pulse R₁ rate constant redox reduction reference electrode Reprinted with permission reversible scan Section semiconductor shown in Figure simulation solution species techniques titration totally irreversible usually voltage voltammetry voltammogram wave zero дх