Electrochemical Methods: Fundamentals and ApplicationsWiley, 2 set 1980 - 736 pagine Takes the student from the most basic chemical and physical principles through fundamentals of thermodynamics, kinetics, and mass transfer, to a thorough treatment of all important experimental methods. Treats application of electrochemical methods to elucidation of reaction mechanisms; double layer structure and surface processes, and their effects on electrode processes are developed from first principles; other key features include a chapter on operational amplifier circuits and electrochemical instrumentation, unique coverage of spectrometric and photochemical experiments, and Laplace transform and digital simulation techniques. Contains numerous examples, illustrations, end-of-chapter problems, references, uniform mathematical notation, and an extensive list of symbols, abbreviations, definitions, and dimensions. |
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Pagina 134
... example , -Jo ( 0 , t ) = i nFA = Do [ aСo ( x , t ) = дх x = 0 = f ( t ) ( 4.3.25 ) The conservation of matter in an electrode reaction can also be used . For example , when O is converted to R at the electrode ( equation 4.3.15 ) ...
... example , -Jo ( 0 , t ) = i nFA = Do [ aСo ( x , t ) = дх x = 0 = f ( t ) ( 4.3.25 ) The conservation of matter in an electrode reaction can also be used . For example , when O is converted to R at the electrode ( equation 4.3.15 ) ...
Pagina 432
... example of this scheme is the reduction of a halonitroaromatic compound in an aprotic medium ( e.g. , in liquid ammonia or N , N - dimethylformamide ) , where the reaction proceeds as follows ( X = Cl , Br , I ) : XC.HạNO , + e = XCH ...
... example of this scheme is the reduction of a halonitroaromatic compound in an aprotic medium ( e.g. , in liquid ammonia or N , N - dimethylformamide ) , where the reaction proceeds as follows ( X = Cl , Br , I ) : XC.HạNO , + e = XCH ...
Pagina 640
... example , p - MoS2 / Fe3 + , Fe2 + / Pt ( 175 ) . Photoelectrosynthetic cells : ( c ) n - type , for example , n - SrTiO3 / H2O / Pt ( H2O → H2 + 102 ) ( 176–178 ) . ( d ) p - type , for example , p - GaP / CO2 ( pH = 6.8 ) / C ...
... example , p - MoS2 / Fe3 + , Fe2 + / Pt ( 175 ) . Photoelectrosynthetic cells : ( c ) n - type , for example , n - SrTiO3 / H2O / Pt ( H2O → H2 + 102 ) ( 176–178 ) . ( d ) p - type , for example , p - GaP / CO2 ( pH = 6.8 ) / C ...
Sommario
Potentials and Thermodynamics of Cells | 44 |
Kinetics of Electrode Reactions | 86 |
Mass Transfer by Migration and Diffusion | 119 |
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Electrochemical Methods: Fundamentals and Applications Allen J. Bard,Larry R. Faulkner Visualizzazione estratti - 1980 |
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A. J. Bard adsorbed adsorption American Chemical Society Anal anodic anthracene applied behavior bulk capacitance cathodic cell charge transfer Chem circuit cm/sec cm² Co(x coefficient components consider coulometric current-potential cyclic cyclic voltammetry density derived diffusion layer disk double-layer drop E₁ effect electroactive electrochemical electrochemical cell Electrochemistry electrode potential electrode processes electrode reaction electrode surface electrolysis electron transfer equation equilibrium example experiment experimental faradaic free energy frequency function hence i-E curve impedance interface involving kinetic limiting current linear mass transfer measurements metal methods n-type semiconductor Nernst equation nernstian obtained overpotential oxidation parameters peak phase platinum plot polarography potential step potentiostat problem pulse R₁ rate constant redox reduction reference electrode Reprinted with permission reversible scan Section semiconductor shown in Figure simulation solution species techniques titration totally irreversible usually voltage voltammetry voltammogram wave zero дх