Electrochemical Methods: Fundamentals and ApplicationsWiley, 2 set 1980 - 736 pagine Takes the student from the most basic chemical and physical principles through fundamentals of thermodynamics, kinetics, and mass transfer, to a thorough treatment of all important experimental methods. Treats application of electrochemical methods to elucidation of reaction mechanisms; double layer structure and surface processes, and their effects on electrode processes are developed from first principles; other key features include a chapter on operational amplifier circuits and electrochemical instrumentation, unique coverage of spectrometric and photochemical experiments, and Laplace transform and digital simulation techniques. Contains numerous examples, illustrations, end-of-chapter problems, references, uniform mathematical notation, and an extensive list of symbols, abbreviations, definitions, and dimensions. |
Dall'interno del libro
Risultati 1-3 di 86
Pagina 363
... function 1 / ī ( s ) s 1/2 vs. s1 / 2 . The slope and intercept of the resulting linear function would provide k , and H. In doing this , we have elected to analyze the system in the s domain , rather than the time domain . To implement ...
... function 1 / ī ( s ) s 1/2 vs. s1 / 2 . The slope and intercept of the resulting linear function would provide k , and H. In doing this , we have elected to analyze the system in the s domain , rather than the time domain . To implement ...
Pagina 666
... function into a series ( 2 , 8 ) when direct usage of the function is impractical because of complexity or when a linear approximation is sought . In general , some point is chosen as a central location , and the expansion represents ...
... function into a series ( 2 , 8 ) when direct usage of the function is impractical because of complexity or when a linear approximation is sought . In general , some point is chosen as a central location , and the expansion represents ...
Pagina 667
... Function of a Single Variable If the function of interest has only a single independent variable , the Taylor formula is a simplified version of ( A.2.1 ) : - Xo f ( x ) = ƒ ( x ) + Σ ¦ ¦ ( x − x ) [ ~ 3 ~ ƒ ] . axi In this case the ...
... Function of a Single Variable If the function of interest has only a single independent variable , the Taylor formula is a simplified version of ( A.2.1 ) : - Xo f ( x ) = ƒ ( x ) + Σ ¦ ¦ ( x − x ) [ ~ 3 ~ ƒ ] . axi In this case the ...
Sommario
Potentials and Thermodynamics of Cells | 44 |
Kinetics of Electrode Reactions | 86 |
Mass Transfer by Migration and Diffusion | 119 |
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Electrochemical Methods: Fundamentals and Applications Allen J. Bard,Larry R. Faulkner Visualizzazione estratti - 1980 |
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A. J. Bard adsorbed adsorption American Chemical Society Anal anodic anthracene applied behavior bulk capacitance cathodic cell charge transfer Chem circuit cm/sec cm² Co(x coefficient components consider coulometric current-potential cyclic cyclic voltammetry density derived diffusion layer disk double-layer drop E₁ effect electroactive electrochemical electrochemical cell Electrochemistry electrode potential electrode processes electrode reaction electrode surface electrolysis electron transfer equation equilibrium example experiment experimental faradaic free energy frequency function hence i-E curve impedance interface involving kinetic limiting current linear mass transfer measurements metal methods n-type semiconductor Nernst equation nernstian obtained overpotential oxidation parameters peak phase platinum plot polarography potential step potentiostat problem pulse R₁ rate constant redox reduction reference electrode Reprinted with permission reversible scan Section semiconductor shown in Figure simulation solution species techniques titration totally irreversible usually voltage voltammetry voltammogram wave zero дх