Electrochemical Methods: Fundamentals and ApplicationsWiley, 2 set 1980 - 736 pagine Takes the student from the most basic chemical and physical principles through fundamentals of thermodynamics, kinetics, and mass transfer, to a thorough treatment of all important experimental methods. Treats application of electrochemical methods to elucidation of reaction mechanisms; double layer structure and surface processes, and their effects on electrode processes are developed from first principles; other key features include a chapter on operational amplifier circuits and electrochemical instrumentation, unique coverage of spectrometric and photochemical experiments, and Laplace transform and digital simulation techniques. Contains numerous examples, illustrations, end-of-chapter problems, references, uniform mathematical notation, and an extensive list of symbols, abbreviations, definitions, and dimensions. |
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Pagina 26
... MASS - TRANSFER - CONTROLLED REACTIONS 1.4.1 Modes of Mass Transfer The simplest electrode reactions are those in which the kinetics of all electron transfer and associated chemical reactions are very rapid compared to those of the mass ...
... MASS - TRANSFER - CONTROLLED REACTIONS 1.4.1 Modes of Mass Transfer The simplest electrode reactions are those in which the kinetics of all electron transfer and associated chemical reactions are very rapid compared to those of the mass ...
Pagina 27
... volume element of solution . The modes of mass transfer are : 1. Migration . Movement of a charged body under the influence of an electric field ( a gradient of electrical potential ) . 2. Diffusion . Movement of a species under the ...
... volume element of solution . The modes of mass transfer are : 1. Migration . Movement of a charged body under the influence of an electric field ( a gradient of electrical potential ) . 2. Diffusion . Movement of a species under the ...
Pagina 119
... Transfer by Migration and Diffusion 4.1 DERIVATION OF GENERAL MASS TRANSFER EQUATION In this section we discuss the general partial differential equations that govern mass transfer ; these will be used frequently in subsequent chapters ...
... Transfer by Migration and Diffusion 4.1 DERIVATION OF GENERAL MASS TRANSFER EQUATION In this section we discuss the general partial differential equations that govern mass transfer ; these will be used frequently in subsequent chapters ...
Sommario
Potentials and Thermodynamics of Cells | 44 |
Kinetics of Electrode Reactions | 86 |
Mass Transfer by Migration and Diffusion | 119 |
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Electrochemical Methods: Fundamentals and Applications Allen J. Bard,Larry R. Faulkner Visualizzazione estratti - 1980 |
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A. J. Bard adsorbed adsorption American Chemical Society Anal anodic anthracene applied behavior bulk capacitance cathodic cell charge transfer Chem circuit cm/sec cm² Co(x coefficient components consider coulometric current-potential cyclic cyclic voltammetry density derived diffusion layer disk double-layer drop E₁ effect electroactive electrochemical electrochemical cell Electrochemistry electrode potential electrode processes electrode reaction electrode surface electrolysis electron transfer equation equilibrium example experiment experimental faradaic free energy frequency function hence i-E curve impedance interface involving kinetic limiting current linear mass transfer measurements metal methods n-type semiconductor Nernst equation nernstian obtained overpotential oxidation parameters peak phase platinum plot polarography potential step potentiostat problem pulse R₁ rate constant redox reduction reference electrode Reprinted with permission reversible scan Section semiconductor shown in Figure simulation solution species techniques titration totally irreversible usually voltage voltammetry voltammogram wave zero дх