Electrochemical Methods: Fundamentals and ApplicationsWiley, 2 set 1980 - 736 pagine Takes the student from the most basic chemical and physical principles through fundamentals of thermodynamics, kinetics, and mass transfer, to a thorough treatment of all important experimental methods. Treats application of electrochemical methods to elucidation of reaction mechanisms; double layer structure and surface processes, and their effects on electrode processes are developed from first principles; other key features include a chapter on operational amplifier circuits and electrochemical instrumentation, unique coverage of spectrometric and photochemical experiments, and Laplace transform and digital simulation techniques. Contains numerous examples, illustrations, end-of-chapter problems, references, uniform mathematical notation, and an extensive list of symbols, abbreviations, definitions, and dimensions. |
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Risultati 1-3 di 54
Pagina 388
... oxidation of Fe2 + falls below 100 % , the next process to occur is Ce3 + → Ce1 + + e . The Ce + so produced is capable of oxidizing any Fe2 + remaining in the bulk solution by the fast reaction Ce ++ Fe2 + → Ce3 ++ Fe3 + ( 10.4.3 ) ...
... oxidation of Fe2 + falls below 100 % , the next process to occur is Ce3 + → Ce1 + + e . The Ce + so produced is capable of oxidizing any Fe2 + remaining in the bulk solution by the fast reaction Ce ++ Fe2 + → Ce3 ++ Fe3 + ( 10.4.3 ) ...
Pagina 539
... an adsorbed oxygen ( or oxide ) layer on platinum inhibits many oxidation processes ( e.g. , the oxidation of hydrogen , oxalic Oxygen region Double- layer 60 90 region | i ( 12.6 Effect of Adsorption of Electroinactive Species 539.
... an adsorbed oxygen ( or oxide ) layer on platinum inhibits many oxidation processes ( e.g. , the oxidation of hydrogen , oxalic Oxygen region Double- layer 60 90 region | i ( 12.6 Effect of Adsorption of Electroinactive Species 539.
Pagina 637
... oxidation of R to O occurs at less positive applied potentials than those required to carry out this process at an inert metal electrode ( curve 3 ) . This apparently easier oxidation represents the contribution of the light energy to ...
... oxidation of R to O occurs at less positive applied potentials than those required to carry out this process at an inert metal electrode ( curve 3 ) . This apparently easier oxidation represents the contribution of the light energy to ...
Sommario
Potentials and Thermodynamics of Cells | 44 |
Kinetics of Electrode Reactions | 86 |
Mass Transfer by Migration and Diffusion | 119 |
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Electrochemical Methods: Fundamentals and Applications Allen J. Bard,Larry R. Faulkner Visualizzazione estratti - 1980 |
Parole e frasi comuni
A. J. Bard adsorbed adsorption American Chemical Society Anal anodic anthracene applied behavior bulk capacitance cathodic cell charge transfer Chem circuit cm/sec cm² Co(x coefficient components consider coulometric current-potential cyclic cyclic voltammetry density derived diffusion layer disk double-layer drop E₁ effect electroactive electrochemical electrochemical cell Electrochemistry electrode potential electrode processes electrode reaction electrode surface electrolysis electron transfer equation equilibrium example experiment experimental faradaic free energy frequency function hence i-E curve impedance interface involving kinetic limiting current linear mass transfer measurements metal methods n-type semiconductor Nernst equation nernstian obtained overpotential oxidation parameters peak phase platinum plot polarography potential step potentiostat problem pulse R₁ rate constant redox reduction reference electrode Reprinted with permission reversible scan Section semiconductor shown in Figure simulation solution species techniques titration totally irreversible usually voltage voltammetry voltammogram wave zero дх