Electrochemical Methods: Fundamentals and ApplicationsWiley, 2 set 1980 - 736 pagine Takes the student from the most basic chemical and physical principles through fundamentals of thermodynamics, kinetics, and mass transfer, to a thorough treatment of all important experimental methods. Treats application of electrochemical methods to elucidation of reaction mechanisms; double layer structure and surface processes, and their effects on electrode processes are developed from first principles; other key features include a chapter on operational amplifier circuits and electrochemical instrumentation, unique coverage of spectrometric and photochemical experiments, and Laplace transform and digital simulation techniques. Contains numerous examples, illustrations, end-of-chapter problems, references, uniform mathematical notation, and an extensive list of symbols, abbreviations, definitions, and dimensions. |
Dall'interno del libro
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Pagina 308
... reduction of oxygen at the platinum disk and also plating of copper by reduction of the Cu ( II ) . ( This plating of copper on the platinum substrate occurs at potentials more positive than those where copper would deposit on bulk ...
... reduction of oxygen at the platinum disk and also plating of copper by reduction of the Cu ( II ) . ( This plating of copper on the platinum substrate occurs at potentials more positive than those where copper would deposit on bulk ...
Pagina 527
... reduction of dissolved O to form a layer of adsorbed R. The wave occurs at potentials more positive than the diffusion - controlled wave , because the free energy of adsorption of R makes reduction of O to adsorbed R easier than to R in ...
... reduction of dissolved O to form a layer of adsorbed R. The wave occurs at potentials more positive than the diffusion - controlled wave , because the free energy of adsorption of R makes reduction of O to adsorbed R easier than to R in ...
Pagina 543
... reduction of Zn ( II ) at a Zn ( Hg ) electrode in aqueous solution ( 99 ) and for the reduction of several aromatic compounds in N , N - dimethylformamide solution ( 106 ) are shown in Table 12.7.1 . Note that for the Zn ( II ) ...
... reduction of Zn ( II ) at a Zn ( Hg ) electrode in aqueous solution ( 99 ) and for the reduction of several aromatic compounds in N , N - dimethylformamide solution ( 106 ) are shown in Table 12.7.1 . Note that for the Zn ( II ) ...
Sommario
Potentials and Thermodynamics of Cells | 44 |
Kinetics of Electrode Reactions | 86 |
Mass Transfer by Migration and Diffusion | 119 |
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Electrochemical Methods: Fundamentals and Applications Allen J. Bard,Larry R. Faulkner Visualizzazione estratti - 1980 |
Parole e frasi comuni
A. J. Bard adsorbed adsorption American Chemical Society Anal anodic anthracene applied behavior bulk capacitance cathodic cell charge transfer Chem circuit cm/sec cm² Co(x coefficient components consider coulometric current-potential cyclic cyclic voltammetry density derived diffusion layer disk double-layer drop E₁ effect electroactive electrochemical electrochemical cell Electrochemistry electrode potential electrode processes electrode reaction electrode surface electrolysis electron transfer equation equilibrium example experiment experimental faradaic free energy frequency function hence i-E curve impedance interface involving kinetic limiting current linear mass transfer measurements metal methods n-type semiconductor Nernst equation nernstian obtained overpotential oxidation parameters peak phase platinum plot polarography potential step potentiostat problem pulse R₁ rate constant redox reduction reference electrode Reprinted with permission reversible scan Section semiconductor shown in Figure simulation solution species techniques titration totally irreversible usually voltage voltammetry voltammogram wave zero дх