Electrochemical Methods: Fundamentals and ApplicationsWiley, 2 set 1980 - 736 pagine Takes the student from the most basic chemical and physical principles through fundamentals of thermodynamics, kinetics, and mass transfer, to a thorough treatment of all important experimental methods. Treats application of electrochemical methods to elucidation of reaction mechanisms; double layer structure and surface processes, and their effects on electrode processes are developed from first principles; other key features include a chapter on operational amplifier circuits and electrochemical instrumentation, unique coverage of spectrometric and photochemical experiments, and Laplace transform and digital simulation techniques. Contains numerous examples, illustrations, end-of-chapter problems, references, uniform mathematical notation, and an extensive list of symbols, abbreviations, definitions, and dimensions. |
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Pagina v
... Techniques - Potential Step Methods 136 6 Controlled Potential Microelectrode Techniques - Potential Sweep Methods 213 7 Controlled Current Microelectrode Techniques 249 8 Methods Involving Forced Convection - Hydrodynamic Methods 280 X ...
... Techniques - Potential Step Methods 136 6 Controlled Potential Microelectrode Techniques - Potential Sweep Methods 213 7 Controlled Current Microelectrode Techniques 249 8 Methods Involving Forced Convection - Hydrodynamic Methods 280 X ...
Pagina 249
... Techniques 7.1 INTRODUCTION We discussed in Chapters 5 and 6 methods in which the potential of an electrode was ... techniques are generally called chronopotentiometric techniques , because E is determined as a function of time , or ...
... Techniques 7.1 INTRODUCTION We discussed in Chapters 5 and 6 methods in which the potential of an electrode was ... techniques are generally called chronopotentiometric techniques , because E is determined as a function of time , or ...
Pagina 316
... techniques . Among the most important are ( a ) an experimental ability to make high - precision measurements because the response may be indefinitely steady and can therefore be averaged over a long term , and ( b ) an ability to treat ...
... techniques . Among the most important are ( a ) an experimental ability to make high - precision measurements because the response may be indefinitely steady and can therefore be averaged over a long term , and ( b ) an ability to treat ...
Sommario
Potentials and Thermodynamics of Cells | 44 |
Kinetics of Electrode Reactions | 86 |
Mass Transfer by Migration and Diffusion | 119 |
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Electrochemical Methods: Fundamentals and Applications Allen J. Bard,Larry R. Faulkner Visualizzazione estratti - 1980 |
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A. J. Bard adsorbed adsorption American Chemical Society Anal anodic anthracene applied behavior bulk capacitance cathodic cell charge transfer Chem circuit cm/sec cm² Co(x coefficient components consider coulometric current-potential cyclic cyclic voltammetry density derived diffusion layer disk double-layer drop E₁ effect electroactive electrochemical electrochemical cell Electrochemistry electrode potential electrode processes electrode reaction electrode surface electrolysis electron transfer equation equilibrium example experiment experimental faradaic free energy frequency function hence i-E curve impedance interface involving kinetic limiting current linear mass transfer measurements metal methods n-type semiconductor Nernst equation nernstian obtained overpotential oxidation parameters peak phase platinum plot polarography potential step potentiostat problem pulse R₁ rate constant redox reduction reference electrode Reprinted with permission reversible scan Section semiconductor shown in Figure simulation solution species techniques titration totally irreversible usually voltage voltammetry voltammogram wave zero дх