Fundamentals of Electrochemical ScienceElsevier Science, 1994 - 474 pagine "Fundamentals of Electrochemical Science is a valuable contribution and I support the publication....I am looking forward to seeing this book on the shelves, and once published, I will not hesitate to recommend itto my students." --ANDRZEJ WIECKOWSKI, University of Illinois at Urbana-Champaign |
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The Conduction of Electricity | 1 |
Ionic Solutions | 45 |
Electrochemical Cells 63 | 65 |
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a.c. current a.c. voltage activation polarization activity coefficient adsorbed Ag(s AgCl(s anions anode applied aqueous solution calculate capacitance capacitor cathode cations cell voltage charge density chemical concentration polarization convection current density current flows diagram discussed in Section dissolved double layer electrical electroactive species electrochemical activities electrochemical cell electrochemistry electrode potential electrode reaction electrode surface electrolyte electronic conductor equal equilibrium constant example experiment faradaic Fick's flux density function Gibbs energy graph hydrogen illustrated impedance interface ionic conductor ionic strength kg mol-1 kinetic Laplace transformation limiting current measured membrane metal mol m-3 negative Nernst equation nonfaradaic null potential O(soln occurs ohmic polarization overvoltage oxidation oxygen phase polarography potential difference predicted Problem rate constant redox reduction reference electrode resistor reversible right-hand semiintegral sin{wt standard electrode potentials steady-state supporting electrolyte thermodynamic transport voltammogram voltmeter zero ΔΕ