Electrochemistry at Solid ElectrodesN. Dekker, 1969 - 402 pagine |
Dall'interno del libro
Risultati 1-3 di 15
Pagina 358
... 1 Medium Source " At CPE At Pte 0.29 M HCIO1 PAP 0.032 0.030 PPD 0.032 0.030 ... 4 sec1 and 4.3 × 10-4 sec ̄1 . [ Hydrolysis data for a number of N , N - dialkyl - p - phenylenediamines are contained in this and continuing studies by Tong et ...
... 1 Medium Source " At CPE At Pte 0.29 M HCIO1 PAP 0.032 0.030 PPD 0.032 0.030 ... 4 sec1 and 4.3 × 10-4 sec ̄1 . [ Hydrolysis data for a number of N , N - dialkyl - p - phenylenediamines are contained in this and continuing studies by Tong et ...
Pagina 359
... 1,4 additions vary with pH because of the pH variation of the precursor hydrolyses . Assuming all three quinoidal forms are available , one can make " ball - park " predictions of the relative 1,4 addition rates . The 1,4 addition has ...
... 1,4 additions vary with pH because of the pH variation of the precursor hydrolyses . Assuming all three quinoidal forms are available , one can make " ball - park " predictions of the relative 1,4 addition rates . The 1,4 addition has ...
Pagina 367
... 1,4 addition of H2O to give the 3 - hydroxy - substituted hydro- quinone . As usual , this is an ECE reaction and the final product is the 2- ( X ) -3 - hydroxybenzoquinone . The rates of the 1,4 addition reactions are readily measured ...
... 1,4 addition of H2O to give the 3 - hydroxy - substituted hydro- quinone . As usual , this is an ECE reaction and the final product is the 2- ( X ) -3 - hydroxybenzoquinone . The rates of the 1,4 addition reactions are readily measured ...
Sommario
APPLICATIONS TO ORGANIC COMPOUNDS | 10 |
Scope and Limitations of Solid Electrodes | 19 |
References | 41 |
Copyright | |
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acetonitrile Acta Anal aniline applied aqueous aromatic benzidine buffer calculated carbon paste electrode cathodic cation radical Chem chemical reaction chronopotentiometry cm²/sec co-workers compounds concentration convection coulometry cyclic voltammetry Delahay diphenylamines Eapp electroactive species electrochemical electrochemistry electrode processes electrode reaction electrode surface electrolyte electron transfer equation evaluation experimental ferrocyanide flow follow-up reactions given H₂SO hydrocarbons hydrodynamic hydrogen hydrolysis I. M. Kolthoff irreversible Khim kinetic Kuwana layer Levich limiting current linear diffusion Lingane mass transport measurements methods Nicholson obtained overpotential oxygen p-aminophenol peak polarogram peak voltammetry perchlorate phenylenediamines Phys platinum platinum electrode polarogram potential potentiostatic quinoneimine R. N. Adams radical ion rate constant ratio reduction Reinmuth residual current reversible Riddiford Shain solid electrode solution solvent stationary electrode studies sulfuric acid supporting electrolyte sweep rate Table techniques V/min values velocity voltage wire electrodes