Differential Optical Absorption Spectroscopy: Principles and Applications

Copertina anteriore
Springer Science & Business Media, 30 mag 2008 - 598 pagine
Light is the essential source of information about the surrounding world for most of us. We see objects of di?erent brightness and colours, or, in scienti?c terms, we distinguish objects by the way they re?ect light of di?erent wa- lengths with varying e?ciency. It was exciting for both of us to learn that scienti?c instruments can expand our senses and provide information from this very same radiation that goes far beyond the simple recognition of - jects. Theabilityto“see”thecompositionoftheairsurroundingusandabove our heads, to us and others, one of the most fascinating aspects of the app- cation of modern technology to study the atmosphere. This fascination drove many of the applications of the Di?erential Optical Absorption Spectroscopy (DOAS) method presented in this book, and continues to be the motivation for many current developments. DOAS is an elegant and powerful analytical method to study the at- sphere and is based on the relatively simple principles of classical absorption spectroscopy. It has therefore always been quite surprising to us that this method has not found wider use in atmospheric research and air-quality m- itoring. We have introduced many university students and researchers to DOAS, often wishing that we could improve our e?orts with a comprehensive text that describes both the theoretical basis and the practical applications of the method.
 

Sommario

Introduction
1
Atmosphere
39
Interaction of Molecules with Radiation
76
Radiation Transport in the Atmosphere
91
Measurement Techniques for Atmospheric Trace
113
Differential Absorption Spectroscopy
135
The Design of DOAS Instruments
175
Evaluation of DOAS Spectra Sensitivity and Detection
287
Yesterday Today and Tomorrow
495
Literature
505
77
531
79
544
87
550
99
557
Spectral Positions of Emission Lines from
569
102
570

Scatteredlight DOAS Measurements
329
Sample Application of Active DOAS with Artificial
378
Sample Application of Passive DOAS
429
Absorption Spectra of Molecules Measurable
573
Index 593
592
Copyright

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